Sun Yueyan, Chen Weiwang, Zhou Xiaomeng
Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response, Civil Aviation University of China Tianjin 300300 P. R. China
RSC Adv. 2021 Oct 27;11(55):34828-34835. doi: 10.1039/d1ra06846f. eCollection 2021 Oct 25.
Kevlar aerogel fibers which inherit the aerogel's brilliant properties of low density, high porosity and large surface area are promising candidates for thermal insulation applications in textiles. To enhance the mechanical strength of Kevlar aerogel fibers, an extra Nomex shell was introduced by a simple coaxial-wet-spinning approach. The resultant coaxial fibers were observed to have a Kevlar aerogel core and a porous Nomex shell. Besides, there also formed an air gap between the core and the shell. This multi-layered coaxial structure with numerous pores inside contributes to the excellent thermal insulation performance of the fibers and their fabrics. The temperature differences between the hot plate and the outer surface of the fabrics were measured to be as high as 80 °C when exposed to a temperature of 300 °C. In addition, these fibers also performed well in thermal stability, and almost did not decompose before 380 °C. Not only that, the breaking strength of the Nomex shell can be up to twice that of the Kevlar core, resulting in a significant improvement in the fiber's mechanical strength. It can be envisaged that the developed coaxial fibers with excellent thermal insulation and endurance properties as well as improved mechanical strength may have broad prospects for thermal insulation at high temperatures.
继承了气凝胶低密度、高孔隙率和大表面积等优异特性的凯夫拉气凝胶纤维,是纺织品隔热应用的理想候选材料。为提高凯夫拉气凝胶纤维的机械强度,通过简单的同轴湿法纺丝方法引入了额外的诺梅克斯外壳。观察到所得的同轴纤维具有凯夫拉气凝胶芯和多孔的诺梅克斯外壳。此外,在芯和外壳之间还形成了气隙。这种内部有大量孔隙的多层同轴结构有助于纤维及其织物具有优异的隔热性能。当暴露在300°C的温度下时,测量得到热板与织物外表面之间的温差高达80°C。此外,这些纤维在热稳定性方面也表现良好,在380°C之前几乎不会分解。不仅如此,诺梅克斯外壳的断裂强度可达凯夫拉芯的两倍,从而使纤维的机械强度得到显著提高。可以设想,所开发的具有优异隔热和耐久性以及提高的机械强度的同轴纤维在高温隔热方面可能具有广阔的前景。