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基于双面混合双金属纳米光栅的薄膜非晶硅太阳能电池中的高效宽带光吸收。

Efficient broadband light absorption in thin-film a-Si solar cell based on double sided hybrid bi-metallic nanogratings.

作者信息

Subhan Fazal E, Khan Aimal Daud, Hilal Fazal E, Khan Adnan Daud, Khan Sultan Daud, Ullah Rehan, Imran Muhammad, Noman Muhammad

机构信息

Center for Advanced Studies in Energy, University of Engineering & Technology Peshawar 25000 Pakistan

College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Soochow University Suzhou 215006 China.

出版信息

RSC Adv. 2020 Mar 24;10(20):11836-11842. doi: 10.1039/c9ra10232a. eCollection 2020 Mar 19.

Abstract

Thin film solar cells (TFSCs) suffer from poor light absorption due to their small thickness, which limits most of their practical applications. Surface plasmons generated by plasmonic nanoparticles offer an opportunity for a low-cost and scalable method to optically engineer TFSCs. Here, a systematic simulation study is conducted to improve the absorption efficiency of amorphous silicon (a-Si) by incorporating double sided plasmonic bi-metallic (Al-Cu) nanogratings. The upper pair of the gratings together with an antireflection coating are responsible for minimizing the reflection losses and enhancing the absorption of low wavelength visible light spectrum in the active layer. The bottom pairs are accountable for increasing the absorption of long wavelength photons in the active layer. In this way, a-Si, which is a poor absorber in the long wavelength region, is now able to absorb broadband light from 670-1060 nm with an average simulated absorption rate of more than 70%, and improved simulated photocurrent density of 22.30 mA cm, respectively. Moreover, simulation results show that the proposed structure reveals many other excellent properties such as small incident angle insensitivity, tunability, and remarkable structural parameters tolerance. Such a design concept is quite versatile and can be extended to other TFSCs.

摘要

薄膜太阳能电池(TFSCs)由于其厚度小而存在光吸收差的问题,这限制了它们的大多数实际应用。等离子体纳米颗粒产生的表面等离子体为光学设计TFSCs提供了一种低成本且可扩展的方法。在此,通过结合双面等离子体双金属(Al-Cu)纳米光栅进行了一项系统的模拟研究,以提高非晶硅(a-Si)的吸收效率。上层光栅与抗反射涂层共同作用,可将反射损失降至最低,并增强有源层中低波长可见光谱的吸收。下层光栅则负责增加有源层中长波长光子的吸收。通过这种方式,在长波长区域吸收能力较差的a-Si现在能够吸收670 - 1060 nm的宽带光,平均模拟吸收率超过70%,模拟光电流密度也分别提高到22.30 mA/cm²。此外,模拟结果表明,所提出的结构还具有许多其他优异特性,如对小入射角不敏感、可调性以及对结构参数有显著的耐受性。这种设计理念具有很强的通用性,可扩展到其他TFSCs。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c414/9050485/803a494db80e/c9ra10232a-f1.jpg

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