Molecular simulations of gas transport in hydrogenated nitrile butadiene rubber and ethylene-propylene-diene rubber.

Diffusion and sorption of five gases (H, N, O, CO, CH) in hydrogenated nitrile butadiene rubber (HNBR) and ethylene-propylene-diene rubber (EPDM) have been investigated by molecular dynamics (MD) and grand canonical Monte Carlo (GCMC) simulations. The diffusion coefficients of gas molecules in HNBR and EPDM are well correlated with the effective penetrant diameter except for CO. CO shows a lower diffusion coefficient due to its linear shape. Additionally, the favorable interaction between CO and HNBR is another factor for its lower diffusion coefficient in HNBR. HNBR shows lower diffusion coefficients than EPDM. This is because the polar -CN groups in HNBR chains increase interchain cohesion and result in tight intermolecular packing, low free volume and poor chain mobility, which decreases the diffusion coefficients of HNBR. The solubility coefficients of CH, O, N and H in HNBR are lower than those in EPDM, which is a result of the weak HNBR-penetrant interactions and low free volume of HNBR. However, the solubility coefficient of CO in HNBR is higher than in EPDM. This is attributed to the strong interaction between CO and HNBR. H, O, N and CH show lower permeability coefficients in HNBR than in EPDM, while CO has higher permeability coefficients in HNBR. These molecular details provide critical information for the understanding of structures and gas transport between HNBR and EPDM.