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具有纳米笼和一维通道的四羧酸锌骨架材料,用于对亚甲基蓝染料进行优异的选择性和有效吸附。

Zinc-tetracarboxylate framework material with nano-cages and one-dimensional channels for excellent selective and effective adsorption of methyl blue dye.

作者信息

Li Qipeng, Qian Jinjie, Du Lin, Zhao Qihua

机构信息

Key Laboratory of Medicinal Chemistry for Natural Resource Education Ministry, School of Chemical Science and Technology, Yunnan University Kunming 650091 P. R. China

Science and Technology Department, College of Chemistry and Chemical Engineering, Zhaotong University Zhaotong 657000 P. R. China.

出版信息

RSC Adv. 2020 Jan 21;10(6):3539-3543. doi: 10.1039/c9ra08983g. eCollection 2020 Jan 16.

Abstract

An example of a zinc-tetracarboxylate framework material (FJI-11) was solvothermally synthesized and structurally characterized. FJI-11 presented 3D cage-stacking frameworks with octahedral cages, cuboctahedral cages and two kinds of 1D channel along the -axis. In addition, FJI-11 exhibited the excellent selective and effective adsorption of methyl blue (MB) dye by guest molecule exchange, and its adsorption process was in accordance with the second-order kinetic model and the Freundlich model.

摘要

通过溶剂热法合成了一种锌四羧酸盐骨架材料(FJI-11)的示例,并对其结构进行了表征。FJI-11呈现出具有八面体笼、立方八面体笼以及沿z轴的两种一维通道的三维笼堆叠骨架。此外,FJI-11通过客体分子交换对亚甲基蓝(MB)染料表现出优异的选择性和有效吸附,其吸附过程符合二级动力学模型和弗伦德里希模型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/870e/9048587/0d0d545c4ac2/c9ra08983g-f1.jpg

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