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石榴石二次离子质谱氧同位素揭示了脉状金矿成因中脉冲岩浆流体及其与大气水混合的关键作用。

Garnet secondary ion mass spectrometry oxygen isotopes reveal crucial roles of pulsed magmatic fluid and its mixing with meteoric water in lode gold genesis.

机构信息

State Key Laboratory of Geological Process and Mineral Resources, China University of Geosciences, Wuhan 430074, China.

School of Earth Resources, China University of Geosciences, Wuhan 430074, China.

出版信息

Proc Natl Acad Sci U S A. 2022 May 10;119(19):e2116380119. doi: 10.1073/pnas.2116380119. Epub 2022 May 2.

DOI:10.1073/pnas.2116380119
PMID:35500124
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9171613/
Abstract

SignificanceThere is a common consensus that lode gold deposits mostly precipitated from metamorphic fluids via fluid boiling and/or fluid-rock interaction, but whether magmatic hydrothermal fluids and the mixing of such fluids with an external component have played a vital role in the formation of lode gold deposits remains elusive. We use garnet secondary ion mass spectrometry oxygen isotope analysis to demonstrate that the world-class Dongping lode gold deposit has been formed by multiple pulses of magmatic hydrothermal fluids and their mixing with large volumes of meteoric water. This study opens an opportunity to tightly constrain the origin of lode gold deposits worldwide and other hydrothermal systems that may have generated giant ore deposits in the Earth's crust.

摘要

意义

人们普遍认为,原生金矿主要是通过变质流体的沸腾和/或流体-岩石相互作用沉淀形成的,但岩浆热液以及这种流体与外部成分的混合是否对原生金矿的形成起到了至关重要的作用,目前仍不得而知。我们利用石榴石二次离子质谱氧同位素分析,证明了世界级的东平原生金矿是由多期岩浆热液及其与大量大气水混合形成的。这项研究为全球范围内的原生金矿以及其他可能在地壳中形成巨型矿床的热液系统的起源提供了一个很好的约束机会。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/b88145d43212/pnas.2116380119fig04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/4e2b379a2883/pnas.2116380119fig01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/5fbe28d0dbe5/pnas.2116380119fig02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/88d0de2160df/pnas.2116380119fig03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/b88145d43212/pnas.2116380119fig04.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/4e2b379a2883/pnas.2116380119fig01.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/5fbe28d0dbe5/pnas.2116380119fig02.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/88d0de2160df/pnas.2116380119fig03.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a1b/9171613/b88145d43212/pnas.2116380119fig04.jpg

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本文引用的文献

1
Tempo of magma degassing and the genesis of porphyry copper deposits.岩浆脱气的时标与斑岩铜矿的成因。
Sci Rep. 2017 Jan 12;7:40566. doi: 10.1038/srep40566.
2
"Wave" signal-smoothing and mercury-removing device for laser ablation quadrupole and multiple collector ICPMS analysis: application to lead isotope analysis.用于激光烧蚀四极杆和多接收电感耦合等离子体质谱分析的“波形”信号平滑和除汞装置:在铅同位素分析中的应用
Anal Chem. 2015 Jan 20;87(2):1152-7. doi: 10.1021/ac503749k. Epub 2014 Dec 29.
3
Isotopic Variations in Meteoric Waters.大气水的同位素变化。
Science. 1961 May 26;133(3465):1702-3. doi: 10.1126/science.133.3465.1702.
4
Gold in magmatic hydrothermal solutions and the rapid formation of a giant ore deposit.岩浆热液中的金与巨型矿床的快速形成。
Science. 2006 Oct 13;314(5797):288-91. doi: 10.1126/science.1132866.