Tarasevich Yuri Yu, Vodolazskaya Irina V, Eserkepov Andrei V
Laboratory of Mathematical Modeling, Astrakhan State University, Astrakhan 414056, Russia.
Phys Chem Chem Phys. 2022 May 18;24(19):11812-11819. doi: 10.1039/d2cp00936f.
The current interest in the study of the 2D systems of randomly deposited metallic nanowires is inspired by a combination of their high electrical conductivity with excellent optical transparency. Metallic nanowire networks show great potential for use in numerous technological applications. Although there are models that describe the electrical conductivity of the random nanowire networks through wire resistance, junction resistance, and number density of nanowires, they are either not rigorously justified or contain fitting parameters. We have proposed a model for the electrical conductivity in random metallic nanowire networks. We have mimicked such random nanowire networks as random resistor networks (RRN) produced by the homogeneous, isotropic, and random deposition of conductive zero-width sticks onto an insulating substrate. We studied the electrical conductivity of these RRNs using a mean-field approximation. An analytical dependency of the electrical conductivity on the main physical parameters (the number density and electrical resistances of these wires and of the junctions between them) has been derived. Computer simulations have been performed to validate our theoretical predictions. We computed the electrical conductivity of the RRNs against the number density of the conductive fillers for the junction-resistance-dominated case and for the case where the wire resistance and the junction resistance were equal. The results of the computations were compared with this mean-field approximation. Our computations demonstrated that our analytical expression correctly predicts the electrical conductivity across a wide range of number densities.
当前对随机沉积金属纳米线二维系统的研究兴趣,源于其高电导率与优异光学透明度的结合。金属纳米线网络在众多技术应用中显示出巨大潜力。尽管有模型通过线电阻、结电阻和纳米线数密度来描述随机纳米线网络的电导率,但这些模型要么没有严格的依据,要么包含拟合参数。我们提出了一种随机金属纳米线网络电导率的模型。我们将这种随机纳米线网络模拟为由导电零宽度棒在绝缘基板上均匀、各向同性且随机沉积产生的随机电阻网络(RRN)。我们使用平均场近似研究了这些RRN的电导率。推导了电导率对主要物理参数(这些线及其之间结的数密度和电阻)的解析依赖关系。进行了计算机模拟以验证我们的理论预测。对于结电阻占主导的情况以及线电阻和结电阻相等的情况,我们计算了RRN的电导率与导电填料数密度的关系。将计算结果与这种平均场近似进行了比较。我们的计算表明,我们的解析表达式在很宽的数密度范围内正确地预测了电导率。