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在绿色溶剂中，通过多孔水热酸催化剂将葡萄糖一锅法转化为乙酰丙酸乙酯。

One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents.

作者信息

Bosilj Monika, Schmidt Johannes, Fischer Anna, White Robin J

机构信息

Fraunhofer Institute for Solar Energy Systems ISE Heidenhofstraße 2 79110 Freiburg im Breisgau Germany

Department of Inorganic and Analytical Chemistry, University of Freiburg Albertstrasse 21 79104 Freiburg Germany.

出版信息

RSC Adv. 2019 Jul 1;9(35):20341-20344. doi: 10.1039/c9ra03902c. eCollection 2019 Jun 25.

DOI:10.1039/c9ra03902c
PMID:35514716
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9065450/
Abstract

The one-pot conversion of glucose to ethyl levulinate over an acid-functionalised hydrothermal catalyst (derived from glucose) provides high initial yields up to 37 mol%, comparable to the homogeneous HSO catalyst, whilst catalyst performance is strongly influenced by green solvent choice.

摘要

在一种酸功能化水热催化剂（由葡萄糖衍生而来）上，葡萄糖一步转化为乙酰丙酸乙酯可提供高达37摩尔%的高初始产率，与均相HSO催化剂相当，同时催化剂性能受绿色溶剂选择的强烈影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/527d/9065450/87e1310f21bc/c9ra03902c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/527d/9065450/fbd91d962b0e/c9ra03902c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/527d/9065450/87e1310f21bc/c9ra03902c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/527d/9065450/fbd91d962b0e/c9ra03902c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/527d/9065450/87e1310f21bc/c9ra03902c-f1.jpg

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Levulinic Acid Biorefineries: New Challenges for Efficient Utilization of Biomass.乙酰丙酸生物精炼厂：生物质高效利用面临的新挑战。
ChemSusChem. 2016 Mar 21;9(6):562-82. doi: 10.1002/cssc.201501405. Epub 2016 Feb 5.
2
Conformal sulfated zirconia monolayer catalysts for the one-pot synthesis of ethyl levulinate from glucose.用于由葡萄糖一锅法合成乙酰丙酸乙酯的共形硫酸化氧化锆单层催化剂。
Chem Commun (Camb). 2014 Oct 11;50(79):11742-5. doi: 10.1039/c4cc04594g.
3
Formation, molecular structure, and morphology of humins in biomass conversion: influence of feedstock and processing conditions.
生物质转化中类腐殖质的形成、分子结构和形态：原料和处理条件的影响。
ChemSusChem. 2013 Sep;6(9):1745-58. doi: 10.1002/cssc.201300332. Epub 2013 Jul 8.
4
Conversion of hemicellulose into furfural using solid acid catalysts in γ-valerolactone.在γ-戊内酯中使用固体酸催化剂将半纤维素转化为糠醛。
Angew Chem Int Ed Engl. 2013 Jan 21;52(4):1270-4. doi: 10.1002/anie.201207334. Epub 2012 Dec 4.
5
Development of heterogeneous catalysts for the conversion of levulinic acid to γ-valerolactone.用于将乙酰丙酸转化为γ-戊内酯的多相催化剂的开发。
ChemSusChem. 2012 Sep;5(9):1657-67. doi: 10.1002/cssc.201200111. Epub 2012 Aug 13.
6
Conversion of mono- and disaccharides to ethyl levulinate and ethyl pyranoside with sulfonic acid-functionalized ionic liquids.磺酸功能化离子液体催化单糖和二糖转化为乙酰丙酸乙酯和吡喃糖苷
ChemSusChem. 2011 Jun 20;4(6):723-6. doi: 10.1002/cssc.201100137. Epub 2011 May 20.
7
Synthesis of carbon-based solid acid microspheres and their application to the production of biodiesel.碳基固体酸微球的合成及其在生物柴油生产中的应用。
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8
Chemical routes for the transformation of biomass into chemicals.将生物质转化为化学品的化学途径。
Chem Rev. 2007 Jun;107(6):2411-502. doi: 10.1021/cr050989d. Epub 2007 May 30.
9
Green chemistry: biodiesel made with sugar catalyst.绿色化学：用糖催化剂制成的生物柴油。
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A carbon material as a strong protonic acid.一种作为强质子酸的碳材料。
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