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Synthesis and structure of [(PhP)Cu(μ-SeCHPh)In(SeCHPh)] as a single-source precursor for the preparation of CuInSe nano-materials.

作者信息

Pal Manoj K, Dey Sandip, Neogy Suman, Kumar Mukesh

机构信息

Chemistry Division, Bhabha Atomic Research Centre India

Mechanical Metallurgy Division, Bhabha Atomic Research Centre India.

出版信息

RSC Adv. 2019 Jun 11;9(32):18302-18307. doi: 10.1039/c9ra03429c. eCollection 2019 Jun 10.

DOI:10.1039/c9ra03429c
PMID:35515225
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064769/
Abstract

The reaction of freshly prepared Na[In(SeCHCH)] with the mixture of CuCl and triphenylphosphine in methanol yielded [(PPh)CuIn(SeCHCH)]. The X-ray structure of the complex revealed the monomeric form of [(PhP)Cu(μ-SeCHPh)In(SeCHPh)] consisting of tetrahedral Cu(i) and In(iii) centers, bridged by two benzyl selenolate ligands. The complex on pyrolysis in a furnace or in oleylamine/HDA yielded tetragonal CuInSe. The morphology and composition of nanostructures were investigated by pXRD, SEM, TEM and EDX analysis. The band gap of the CuInSe nanostructures, obtained from pyrolysis in HDA and OA has been deduced from DRS as 1.85 and 1.86 eV, respectively.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/ee26a34bb39b/c9ra03429c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/029cdd08391e/c9ra03429c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/a0077043fd69/c9ra03429c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/83d8cfd72fb1/c9ra03429c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/a4fb31f38667/c9ra03429c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/f03c2e3f2735/c9ra03429c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/ee26a34bb39b/c9ra03429c-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/029cdd08391e/c9ra03429c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/a0077043fd69/c9ra03429c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/83d8cfd72fb1/c9ra03429c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/a4fb31f38667/c9ra03429c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/f03c2e3f2735/c9ra03429c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1536/9064769/ee26a34bb39b/c9ra03429c-f5.jpg

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