Jamil Muhammad Imran, Song Lina, Zhu Juan, Ahmed Numan, Zhan Xiaoli, Chen Fengqiu, Cheng Dangguo, Zhang Qinghua
Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University Hangzhou 310027 China
Institute of Zhejiang University-Quzhou 324000 Quzhou China.
RSC Adv. 2020 May 20;10(33):19157-19168. doi: 10.1039/d0ra01786h.
Creating a robust omniphobic surface that repels various liquids would have broad technological implications for areas ranging from biomedical devices and fuel transport to architecture. The present omniphobic surfaces still have the problems of complex fabrication methods, high cost, and being environmentally harmful. To address these challenges, here we report a novel process to design a non-fluorinated, long-term slippery omniphobic surface of candle soot nanoparticles with a silicone binder that cures at room temperature. The porosity, nanoscale roughness, strong affinity of the substrate with the silicone lubricant, and retention of lubricant after curing of the binder play an important role in its stability and low ice adhesion strength at sub-zero temperature. The developed surface exhibits damage resistant slippery properties, repellency to several liquids with different surface tensions including blood, delay in freezing point along with ultra-low ice adhesion strength (2 kPa) and maintains it even below 7 kPa under harsh environmental conditions; 90 frosting/defrosting cycles at -90 °C; 2 months under an ice layer; 2 months at 60 °C; 9 days flow in acidic/basic water and exposure to super-cold water. In addition, this novel technique is cheap, easy to fabricate, environmentally benign and suitable for large-scale applications.
创造一种能排斥各种液体的坚固超疏水表面,将对从生物医学设备、燃料运输到建筑等诸多领域产生广泛的技术影响。目前的超疏水表面仍存在制造方法复杂、成本高以及对环境有害等问题。为应对这些挑战,我们在此报告一种新颖的工艺,用于设计一种由蜡烛烟灰纳米颗粒与室温固化的硅树脂粘合剂组成的非氟化、长期具有滑爽性的超疏水表面。孔隙率、纳米级粗糙度、基材与硅树脂润滑剂的强亲和力以及粘合剂固化后润滑剂的保留,对其在零下温度下的稳定性和低冰粘附强度起着重要作用。所开发的表面具有抗损伤的滑爽性能,能排斥包括血液在内的几种具有不同表面张力的液体,具有冰点延迟以及超低的冰粘附强度(2千帕),并且在恶劣环境条件下甚至在7千帕以下仍能保持;在-90°C下进行90次结霜/除霜循环;在冰层下放置2个月;在60°C下放置2个月;在酸性/碱性水中流动9天并暴露于过冷水。此外,这种新颖的技术成本低廉、易于制造、对环境无害且适用于大规模应用。