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具有改善热导率的银纳米粒子/多壁碳纳米管复合改性银-环氧糊剂。

Ag-NPs/MWCNT composite-modified silver-epoxy paste with improved thermal conductivity.

作者信息

Li Yanchao, Gan Guoyou, Huang Yukuan, Yu Xianglei, Cheng Junhua, Liu Chengbin

机构信息

School of Material Science and Engineering, Kunming University of Science and Technology, Key Laboratory of Advanced Materials of Yunnan Province Kunming 650093 Yunnan China

出版信息

RSC Adv. 2019 Jul 2;9(36):20663-20669. doi: 10.1039/c9ra03090e. eCollection 2019 Jul 1.

Abstract

Heat dissipation is a critical issue in high-performance electronics, which needs to be solved, and an electronic paste is a good choice to solve this issue. In this paper, silver nanoparticles/multi-walled carbon nanotube (Ag-NPs/MWCNT) composites were prepared by the chemical process for the modification of electronic pastes. The micromorphology and spectral analysis of the as-prepared Ag-NPs/MWCNT composites indicated that Ag-NPs were uniformly distributed on the MWCNT surfaces with high distribution densities; the average size of Ag-NPs was estimated to be 8.29 nm. The as-obtained Ag-NPs/MWCNT composites were then added to a silver-epoxy paste. Field emission scanning electron microscopy (FESEM), thermogravimetry (TG) and thermal conductivity analyses suggested the incorporation of Ag-NPs/MWCNT composites in the silver-epoxy paste; Ag flakes were better connected by Ag-NPs/MWCNTs, which improved the thermal conductivity of the paste from 0.73 to 0.96 W m K. However, more weight loss was observed when Ag-NPs/MWCNTs were incorporated in the silver-epoxy paste. Overall, the addition of Ag-NPs/MWCNTs into the silver-epoxy paste increased the thermal conductivity, which can be applied to high-performance electronics.

摘要

散热是高性能电子领域的一个关键问题,亟待解决,而电子浆料是解决这一问题的一个不错选择。本文通过化学方法制备了银纳米颗粒/多壁碳纳米管(Ag-NPs/MWCNT)复合材料用于电子浆料的改性。所制备的Ag-NPs/MWCNT复合材料的微观形貌和光谱分析表明,Ag-NPs以高分布密度均匀分布在MWCNT表面;Ag-NPs的平均尺寸估计为8.29 nm。然后将所得到的Ag-NPs/MWCNT复合材料添加到银-环氧浆料中。场发射扫描电子显微镜(FESEM)、热重分析(TG)和热导率分析表明Ag-NPs/MWCNT复合材料已掺入银-环氧浆料中;Ag-NPs/MWCNTs使银片连接得更好,从而将浆料的热导率从0.73提高到0.96 W m⁻¹ K⁻¹。然而,当将Ag-NPs/MWCNTs掺入银-环氧浆料中时,观察到更多的重量损失。总体而言,向银-环氧浆料中添加Ag-NPs/MWCNTs提高了热导率,可应用于高性能电子领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/85a1/9065797/dada53574a0e/c9ra03090e-f1.jpg

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