Synthesis and catalytic performance of a small crystal NaY zeolite with high SiO/AlO ratio.

A small crystal NaY zeolite with a high SiO/AlO ratio was successfully synthesized with seeding and without organic template, and the effects of the silicon source, aging time and NaO seeding content on the crystal size of NaY zeolite were investigated. The synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-Transform Infrared (FT-IR) spectroscopy and N adsorption-desorption. The results showed that the silicon source used to prepare seeding had a great effect on the crystal size of NaY zeolite, NaY zeolite with average size of 100 nm and SiO/AlO ratio of 5.42 was obtained by using the seeding prepared with silica sol. Moreover, the crystal size of NaY zeolite decreased with an extension of the aging time and an increase of the NaO content of seeding. The catalytic performance of small crystal Y zeolite was evaluated in the hydrocracking of vacuum gas oil (VGO), the catalyst with smaller crystal Y zeolite presented higher VGO conversion and middle distillates selectivity than those with larger ones due to its higher surface area and more amount of mesoporous.