• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

碳纳米管改性层状α-二氧化锰复合阻燃剂：制备及其在环氧树脂阻燃中的性能

CNT modified layered α-MnO hybrid flame retardants: preparation and their performance in the flame retardancy of epoxy resins.

作者信息

Qian Xiaodong, Shi Congling, Jing Jingyun

机构信息

Beijing Key Laboratory of Metro Fire and Passenger Transportation Safety, China Academy of Safety Science and Technology Beijing 100012 China

出版信息

RSC Adv. 2020 Jul 21;10(46):27408-27417. doi: 10.1039/d0ra03654d.

DOI:10.1039/d0ra03654d
PMID:35516958
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9055619/
Abstract

In this paper, CNT modified layered α-MnO hybrid flame retardants (α-MnO-CNTs) were synthesized through one-pot preparation. The structure and composition of the α-MnO-CNTs hybrid flame retardants were investigated by X-ray diffraction, TEM and SEM. Subsequently, the α-MnO-CNTs hybrids were then incorporated into epoxy resin (EP) to improve the fire safety properties. Compared with pure EP and the composites with CNTs or α-MnO, EP/α-MnO-CNTs composites exhibited improved flame retardancy and smoke suppression properties. With the incorporation of only 2.0 wt% of α-MnO-CNTs hybrid flame retardants, the peak heat release rate and total heat release of the composites showed 34% and 10.7% reduction respectively. In addition, the volatile gases such as CO and CO were reduced and the smoke generation was also effectively inhibited. The improved fire safety of the composites is generally due to the network structures and the synergistic effect of α-MnO and CNTs, the catalyzing charring effect, smoke suppression and the physical barrier effect of α-MnO nanosheets.

摘要

在本文中，通过一锅法制备了碳纳米管（CNT）改性的层状α-二氧化锰杂化阻燃剂（α-MnO-CNTs）。采用X射线衍射、透射电子显微镜（TEM）和扫描电子显微镜（SEM）对α-MnO-CNTs杂化阻燃剂的结构和组成进行了研究。随后，将α-MnO-CNTs杂化物加入到环氧树脂（EP）中以提高其防火性能。与纯EP以及含有CNTs或α-MnO的复合材料相比，EP/α-MnO-CNTs复合材料表现出更好的阻燃性和抑烟性能。仅加入2.0 wt%的α-MnO-CNTs杂化阻燃剂时，复合材料的热释放峰值速率和总热释放量分别降低了34%和10.7%。此外，一氧化碳（CO）等挥发性气体减少，烟雾生成也得到有效抑制。复合材料防火性能的提高通常归因于网络结构以及α-MnO和CNTs的协同效应、α-MnO纳米片的催化成炭效应、抑烟作用和物理阻隔效应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/1c0927e27a66/d0ra03654d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/3c35810496fa/d0ra03654d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/754e6022199c/d0ra03654d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/da59aa25aa70/d0ra03654d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/2b10767a66fa/d0ra03654d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/b96f81a4125f/d0ra03654d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/8147a7e4a681/d0ra03654d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/214afd7a980b/d0ra03654d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/7fc81a9c810d/d0ra03654d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/d0ca10e35c3f/d0ra03654d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/918b9a903153/d0ra03654d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/2f623f0b1265/d0ra03654d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/e15b2c05a71a/d0ra03654d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/04d735197ac2/d0ra03654d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/1c0927e27a66/d0ra03654d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/3c35810496fa/d0ra03654d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/754e6022199c/d0ra03654d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/da59aa25aa70/d0ra03654d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/2b10767a66fa/d0ra03654d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/b96f81a4125f/d0ra03654d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/8147a7e4a681/d0ra03654d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/214afd7a980b/d0ra03654d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/7fc81a9c810d/d0ra03654d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/d0ca10e35c3f/d0ra03654d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/918b9a903153/d0ra03654d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/2f623f0b1265/d0ra03654d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/e15b2c05a71a/d0ra03654d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/04d735197ac2/d0ra03654d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4140/9055619/1c0927e27a66/d0ra03654d-s2.jpg

相似文献

1
CNT modified layered α-MnO hybrid flame retardants: preparation and their performance in the flame retardancy of epoxy resins.碳纳米管改性层状α-二氧化锰复合阻燃剂：制备及其在环氧树脂阻燃中的性能
RSC Adv. 2020 Jul 21;10(46):27408-27417. doi: 10.1039/d0ra03654d.
2
DOPO/Silicon/CNT Nanohybrid Flame Retardants: Toward Improving the Fire Safety of Epoxy Resins.9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物/硅/碳纳米管纳米杂化阻燃剂：用于提高环氧树脂的消防安全性能
Polymers (Basel). 2022 Jan 30;14(3):565. doi: 10.3390/polym14030565.
3
Zinc Hydroxystannate/Carbon Nanotube Hybrids as Flame Retardant and Smoke Suppressant for Epoxy Resins.羟基锡酸锌/碳纳米管杂化物作为环氧树脂的阻燃剂和抑烟剂
Molecules. 2023 Sep 27;28(19):6820. doi: 10.3390/molecules28196820.
4
MoS2 nanolayers grown on carbon nanotubes: an advanced reinforcement for epoxy composites.生长在碳纳米管上的二硫化钼纳米层：用于环氧复合材料的一种先进增强材料。
ACS Appl Mater Interfaces. 2015 Mar 25;7(11):6070-81. doi: 10.1021/acsami.5b00762. Epub 2015 Mar 12.
5
Synergistic Effect of Multifunctional Layered Double Hydroxide-Based Hybrids and Modified Phosphagen with an Active Amino Group for Enhancing the Smoke Suppression and Flame Retardancy of Epoxy.基于多功能层状双氢氧化物的杂化物与具有活性氨基的改性磷源对增强环氧树脂抑烟和阻燃性能的协同效应。
ACS Omega. 2022 Jun 16;7(25):21714-21726. doi: 10.1021/acsomega.2c01719. eCollection 2022 Jun 28.
6
Preparation of Naphthalene-Based Flame Retardant for High Fire Safety and Smoke Suppression of Epoxy Resin.制备萘基阻燃剂以提高环氧树脂的高防火安全性和抑烟性。
Molecules. 2023 May 24;28(11):4287. doi: 10.3390/molecules28114287.
7
Design of Hierarchically Tailored Hybrids Based on Nickle Nanocrystal-Decorated Manganese Dioxides for Enhanced Fire Safety of Epoxy Resin.基于镍纳米晶修饰的二氧化锰的分级定制杂化材料设计用于增强环氧树脂的防火安全性。
Int J Mol Sci. 2022 Nov 8;23(22):13711. doi: 10.3390/ijms232213711.
8
Effect of Layered Aminovanadic Oxalate Phosphate on Flame Retardancy of Epoxy Resin.层状氨基钒酸氧代磷酸酯对环氧树脂阻燃性能的影响。
Molecules. 2023 Apr 9;28(8):3322. doi: 10.3390/molecules28083322.
9
Enhancing Flame Retardancy and Smoke Suppression in Epoxy Resin Composites with Sulfur-Phosphorous Reactive Flame Retardant.用硫-磷反应型阻燃剂提高环氧树脂复合材料的阻燃性和抑烟性
Molecules. 2023 Dec 31;29(1):227. doi: 10.3390/molecules29010227.
10
Improving Flame Retardancy of Epoxy Resin Nanocomposites by Carbon Nanotubes Grafted CuAl-Layered Double Hydroxide Hybrid.通过碳纳米管接枝的 CuAl 层状双氢氧化物杂化物提高环氧树脂纳米复合材料的阻燃性。
J Nanosci Nanotechnol. 2020 Oct 1;20(10):6406-6412. doi: 10.1166/jnn.2020.18120.

本文引用的文献

1
In situ growth of 0D silica nanospheres on 2D molybdenum disulfide nanosheets: Towards reducing fire hazards of epoxy resin.在二维二硫化钼纳米片上原位生长 0D 硅纳米球：降低环氧树脂的火灾隐患。
J Hazard Mater. 2018 Feb 15;344:1078-1089. doi: 10.1016/j.jhazmat.2017.11.059. Epub 2017 Dec 2.
2
Functionalized Carbon Nanotubes with Phosphorus- and Nitrogen-Containing Agents: Effective Reinforcer for Thermal, Mechanical, and Flame-Retardant Properties of Polystyrene Nanocomposites.含磷、氮试剂功能化的碳纳米管：有效增强聚苯乙烯纳米复合材料的热、机械和阻燃性能。
ACS Appl Mater Interfaces. 2016 Oct 5;8(39):26266-26274. doi: 10.1021/acsami.6b06864. Epub 2016 Sep 21.
3
Recent Progress on Ferroelectric Polymer-Based Nanocomposites for High Energy Density Capacitors: Synthesis, Dielectric Properties, and Future Aspects.
基于铁电聚合物的用于高能量密度电容器的纳米复合材料的最新进展：合成、介电性能和未来展望。
Chem Rev. 2016 Apr 13;116(7):4260-317. doi: 10.1021/acs.chemrev.5b00495. Epub 2016 Apr 4.
4
Construction of Hierarchical α-MnO2 Nanowires@Ultrathin δ-MnO2 Nanosheets Core-Shell Nanostructure with Excellent Cycling Stability for High-Power Asymmetric Supercapacitor Electrodes.构建具有优异循环稳定性的分层α-MnO2 纳米线@超薄 δ-MnO2 纳米片核壳结构纳米结构，用于高性能非对称超级电容器电极。
ACS Appl Mater Interfaces. 2016 Apr 13;8(14):9050-8. doi: 10.1021/acsami.5b11300. Epub 2016 Apr 4.
5
Asynchronous Crystal Cell Expansion during Lithiation of K(+)-Stabilized α-MnO2.钾离子稳定化α-MnO2 嵌锂过程中的非同步晶胞膨胀
Nano Lett. 2015 May 13;15(5):2998-3007. doi: 10.1021/nl5048913. Epub 2015 Apr 16.
6
Graphene-multilayer graphene nanocomposites as highly efficient thermal interface materials.石墨烯-多层石墨烯纳米复合材料作为高效的热界面材料。
Nano Lett. 2012 Feb 8;12(2):861-7. doi: 10.1021/nl203906r. Epub 2012 Jan 17.
7
Synergistic effects of zirconia-coated carbon nanotube on crystalline structure of polyvinylidene fluoride nanocomposites: electrical properties and flame-retardant behavior.氧化锆包覆碳纳米管对聚偏氟乙烯纳米复合材料结晶结构的协同作用：电性能和阻燃性能。
Langmuir. 2010 Mar 2;26(5):3609-14. doi: 10.1021/la903022j.
8
Room-temperature synthesis of manganese oxide monosheets.室温下合成氧化锰单分子层。
J Am Chem Soc. 2008 Nov 26;130(47):15938-43. doi: 10.1021/ja804503f.
9
Purity assessment of single-wall carbon nanotubes, using optical absorption spectroscopy.使用光吸收光谱法对单壁碳纳米管进行纯度评估。
J Phys Chem B. 2005 May 26;109(20):9952-65. doi: 10.1021/jp044990c.
10
Nanoparticle networks reduce the flammability of polymer nanocomposites.纳米颗粒网络降低了聚合物纳米复合材料的可燃性。
Nat Mater. 2005 Dec;4(12):928-33. doi: 10.1038/nmat1502. Epub 2005 Oct 23.