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含有双子型离子液体作为多重氢键交联剂的坚韧且可拉伸的无机/有机双网络离子凝胶。

Tough and stretchable inorganic/organic double network ion gel containing gemini-type ionic liquid as a multiple hydrogen bond cross-linker.

作者信息

Yasui Tomoki, Kamio Eiji, Matsuyama Hideto

机构信息

Center for Membrane and Film Technology, Department of Chemical Science and Engineering, Kobe University 1-1 Rokkodai-cho, Nada-ku Kobe 657-8501 Japan

出版信息

RSC Adv. 2019 Apr 16;9(21):11870-11876. doi: 10.1039/c9ra01790a. eCollection 2019 Apr 12.

DOI:10.1039/c9ra01790a
PMID:35517029
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9063469/
Abstract

Tough and stretchable inorganic/organic double network ion gels containing gemini-type ionic liquids with two OH groups in the di-cation, which can work as multiple hydrogen bond-based weak cross-linkers of the gel networks, are developed.

摘要

开发出了坚韧且可拉伸的无机/有机双网络离子凝胶，其包含在双阳离子中有两个羟基的双子型离子液体，该离子液体可作为凝胶网络中基于多重氢键的弱交联剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e2b24ad170f7/c9ra01790a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/8c5586005153/c9ra01790a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/d85c2344daba/c9ra01790a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e4d06be5b9ce/c9ra01790a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e6859f28b607/c9ra01790a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/a60d268b3985/c9ra01790a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/612816697528/c9ra01790a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/eb631a94a4fe/c9ra01790a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e2b24ad170f7/c9ra01790a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/8c5586005153/c9ra01790a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/d85c2344daba/c9ra01790a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e4d06be5b9ce/c9ra01790a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e6859f28b607/c9ra01790a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/a60d268b3985/c9ra01790a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/612816697528/c9ra01790a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/eb631a94a4fe/c9ra01790a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e12/9063469/e2b24ad170f7/c9ra01790a-f8.jpg

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本文引用的文献

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ACS Macro Lett. 2013 Dec 17;2(12):1100-1104. doi: 10.1021/mz4005265. Epub 2013 Dec 6.
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Inorganic/Organic Double-Network Ion Gels with Partially Developed Silica-Particle Network.具有部分发展的硅粒子网络的无机/有机双重网络离子凝胶。
Langmuir. 2018 Sep 11;34(36):10622-10633. doi: 10.1021/acs.langmuir.8b01930. Epub 2018 Aug 29.
3
Self-Healing Micellar Ion Gels Based on Multiple Hydrogen Bonding.
基于多重氢键的自修复胶束离子凝胶
Adv Mater. 2018 Jul 31:e1802792. doi: 10.1002/adma.201802792.
4
Inorganic/Organic Double-Network Gels Containing Ionic Liquids.含离子液体的无机/有机双网络凝胶。
Adv Mater. 2017 Dec;29(47). doi: 10.1002/adma.201704118. Epub 2017 Nov 8.
5
An amino acid ionic liquid-based tough ion gel membrane for CO2 capture.一种用于二氧化碳捕获的基于氨基酸离子液体的坚韧离子凝胶膜。
Chem Commun (Camb). 2015 Sep 14;51(71):13658-61. doi: 10.1039/c5cc04841a.
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Increasing the maximum achievable strain of a covalent polymer gel through the addition of mechanically invisible cross-links.通过添加力学上不可见的交联点来提高共价聚合物凝胶的最大可实现应变。
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Polymeric ion-gels containing an amino acid ionic liquid for facilitated CO2 transport media.含氨基酸离子液体的聚合物离子凝胶，用于促进 CO2 传输介质。
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