• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

一种新型可交联侧链磺化聚芳醚砜共聚物质子交换膜的合成与表征

Synthesis and characterization of a novel crosslinkable side-chain sulfonated poly(arylene ether sulfone) copolymer proton exchange membranes.

作者信息

Wang Shouping, He Fugang, Weng Qiang, Yuan Diao, Chen Pei, Chen Xinbing, An Zhongwei

机构信息

Key Laboratory of Applied Surface and Colloid Chemistry (MOE), Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University Xi'an 710119 PR China

出版信息

RSC Adv. 2020 Jun 30;10(42):24772-24783. doi: 10.1039/d0ra02987d. eCollection 2020 Jun 29.

DOI:10.1039/d0ra02987d
PMID:35517481
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9055182/
Abstract

A series of novel crosslinkable side-chain sulfonated poly(arylene ether sulfone) copolymers (S-SPAES(/)) was prepared from 4,4'-biphenol, 4,4'-difluorodiphenyl sulfone, and a new difluoro aromatic monomer 1-(2,6-difluorophenyl)-2-(3,5-dimethoxyphenyl)-1,2-ethanedione (DFDMED) co-polycondensation, demethylation, and further nucleophilic substitution of 1,4-butane sultone. Meanwhile, quinoxaline-based crosslinked copolymers (CS-SPAES(/)) were obtained cyclo-condensation between S-SPAES(/) and 3,3'-diaminobenzidine. Both the crosslinkable and crosslinked copolymer membranes exhibit good mechanical properties and high anisotropic membrane swelling. Crosslinkable S-SPAES(1/2) with an ion exchange capacity (IEC) of 2.01 mequiv. g displays a relatively high proton conductivity of 180 mS cm and acceptable single-cell performance, which is attributed to its good microphase separation resulting from the side-chain sulfonated copolymer structures. Compared with S-SPAES(1/1) (IEC of 1.68 mequiv. g), crosslinked CS-SPAES(1/2) with a comparable IEC exhibits a larger conductivity of 157 mS cm, and significantly higher oxidative stability and lower membrane swelling, suggesting a distinct performance improvement due to the quinoxaline-based crosslinking.

摘要

通过4,4'-双酚、4,4'-二氟二苯砜与新型二氟芳香单体1-(2,6-二氟苯基)-2-(3,5-二甲氧基苯基)-1,2-乙二酮(DFDMED)的共缩聚、脱甲基以及1,4-丁烷磺内酯的进一步亲核取代反应，制备了一系列新型可交联的侧链磺化聚(亚芳基醚砜)共聚物(S-SPAES(/))。同时，通过S-SPAES(/)与3,3'-二氨基联苯胺的环缩合反应得到了基于喹喔啉的交联共聚物(CS-SPAES(/))。可交联和交联共聚物膜均表现出良好的机械性能和高各向异性的膜溶胀性。离子交换容量(IEC)为2.01 mequiv. g的可交联S-SPAES(1/2)显示出相对较高的质子传导率180 mS cm以及可接受的单电池性能，这归因于其侧链磺化共聚物结构导致的良好微相分离。与IEC为1.68 mequiv. g的S-SPAES(1/1)相比，具有相当IEC的交联CS-SPAES(1/2)表现出更大的传导率157 mS cm，以及显著更高的氧化稳定性和更低的膜溶胀性，表明基于喹喔啉的交联使其性能有明显改善。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/87b498c06098/d0ra02987d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/4071edb56447/d0ra02987d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/064166a46a78/d0ra02987d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/f4b4a2d6c059/d0ra02987d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/7610ea952527/d0ra02987d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/48dcb977c7e2/d0ra02987d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/2ff2df0f81b3/d0ra02987d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/fad030016a1c/d0ra02987d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/a4bfa5568f70/d0ra02987d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/9bd9dbbc122e/d0ra02987d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/894f0eb7a35b/d0ra02987d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/6ced91e993bb/d0ra02987d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/32b2d1fc6495/d0ra02987d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/c60c3818ddae/d0ra02987d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/87b498c06098/d0ra02987d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/4071edb56447/d0ra02987d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/064166a46a78/d0ra02987d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/f4b4a2d6c059/d0ra02987d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/7610ea952527/d0ra02987d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/48dcb977c7e2/d0ra02987d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/2ff2df0f81b3/d0ra02987d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/fad030016a1c/d0ra02987d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/a4bfa5568f70/d0ra02987d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/9bd9dbbc122e/d0ra02987d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/894f0eb7a35b/d0ra02987d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/6ced91e993bb/d0ra02987d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/32b2d1fc6495/d0ra02987d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/c60c3818ddae/d0ra02987d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f25/9055182/87b498c06098/d0ra02987d-f11.jpg

相似文献

1
Synthesis and characterization of a novel crosslinkable side-chain sulfonated poly(arylene ether sulfone) copolymer proton exchange membranes.一种新型可交联侧链磺化聚芳醚砜共聚物质子交换膜的合成与表征
RSC Adv. 2020 Jun 30;10(42):24772-24783. doi: 10.1039/d0ra02987d. eCollection 2020 Jun 29.
2
Morphological Effect of Side Chain Length in Sulfonated Poly(arylene ether sulfone)s Polymer Electrolyte Membranes via Molecular Dynamics Simulation.通过分子动力学模拟研究磺化聚芳醚砜类聚合物电解质膜侧链长度的形态学效应
Polymers (Basel). 2022 Dec 15;14(24):5499. doi: 10.3390/polym14245499.
3
Enhanced Ion Cluster Size of Sulfonated Poly (Arylene Ether Sulfone) for Proton Exchange Membrane Fuel Cell Application.用于质子交换膜燃料电池应用的磺化聚（亚芳基醚砜）的增强离子簇尺寸
Polymers (Basel). 2021 Mar 31;13(7):1111. doi: 10.3390/polym13071111.
4
Cross-Linked Sulfonated Poly(arylene ether sulfone) Containing a Flexible and Hydrophobic Bishydroxy Perfluoropolyether Cross-Linker for High-Performance Proton Exchange Membrane.交联磺化聚（芳基醚砜）含柔性疏水双羟全氟聚醚交联剂的高性能质子交换膜
ACS Appl Mater Interfaces. 2018 Jul 5;10(26):21788-21793. doi: 10.1021/acsami.8b05139. Epub 2018 Jun 19.
5
Considerations of the Effects of Naphthalene Moieties on the Design of Proton-Conductive Poly(arylene ether ketone) Membranes for Direct Methanol Fuel Cells.考虑萘环部分对直接甲醇燃料电池质子传导聚（芳基醚酮）膜设计的影响。
ACS Appl Mater Interfaces. 2016 Sep 14;8(36):24079-88. doi: 10.1021/acsami.6b06983. Epub 2016 Sep 2.
6
Sulfonated poly(arylene ether sulfone)s with phosphine oxide moieties: a promising material for proton exchange membranes.含膦氧化物的磺化聚（芳基醚砜）：质子交换膜的一种有前途的材料。
ACS Appl Mater Interfaces. 2010 Jun;2(6):1601-7. doi: 10.1021/am1000739.
7
Synthesis and properties of sulfonated block copolymers having fluorenyl groups for fuel-cell applications.用于燃料电池的具有芴基的磺化嵌段共聚物的合成与性能。
ACS Appl Mater Interfaces. 2009 Jun;1(6):1279-86. doi: 10.1021/am900165w.
8
Property Enhancement Effects of Side-Chain-Type Naphthalene-Based Sulfonated Poly(arylene ether ketone) on Nafion Composite Membranes for Direct Methanol Fuel Cells.侧链型萘基磺化聚芳醚酮对用于直接甲醇燃料电池的 Nafion 复合膜的性能增强作用。
ACS Appl Mater Interfaces. 2017 Sep 20;9(37):32227-32236. doi: 10.1021/acsami.7b08566. Epub 2017 Sep 7.
9
Graft-crosslinked copolymers based on poly(arylene ether ketone)-gc-sulfonated poly(arylene ether sulfone) for PEMFC applications.用于 PEMFC 应用的基于聚（芳基醚酮）-gc-磺化聚（芳基醚砜）的接枝交联共聚物。
Macromol Rapid Commun. 2011 Jul 15;32(14):1108-13. doi: 10.1002/marc.201100116. Epub 2011 Jun 13.
10
Synthesis of Sulfonated Poly(Arylene Ether Sulfone)s Containing Aliphatic Moieties for Effective Membrane Electrode Assembly Fabrication by Low-Temperature Decal Transfer Methods.通过低温贴花转移法合成含脂肪族基团的磺化聚（亚芳基醚砜）用于高效膜电极组件制备
Polymers (Basel). 2021 May 24;13(11):1713. doi: 10.3390/polym13111713.

本文引用的文献

1
Cross-Linked Sulfonated Poly(arylene ether sulfone) Containing a Flexible and Hydrophobic Bishydroxy Perfluoropolyether Cross-Linker for High-Performance Proton Exchange Membrane.交联磺化聚（芳基醚砜）含柔性疏水双羟全氟聚醚交联剂的高性能质子交换膜
ACS Appl Mater Interfaces. 2018 Jul 5;10(26):21788-21793. doi: 10.1021/acsami.8b05139. Epub 2018 Jun 19.
2
Enhanced Performance of a Sulfonated Poly(arylene ether ketone) Block Copolymer Bearing Pendant Sulfonic Acid Groups for Polymer Electrolyte Membrane Fuel Cells Operating at 80% Relative Humidity.在 80%相对湿度下运行的聚合物电解质膜燃料电池中，具有支化磺酸基团的磺化聚（芳基醚酮）嵌段共聚物的性能得到提高。
ACS Appl Mater Interfaces. 2018 Jun 20;10(24):20835-20844. doi: 10.1021/acsami.8b03790. Epub 2018 Jun 6.
3
Highly Proton Conducting Polyelectrolyte Membranes with Unusual Water Swelling Behavior Based on Triptycene-containing Poly(arylene ether sulfone) Multiblock Copolymers.基于含三茀的聚（芳基醚砜）多嵌段共聚物的具有异常水溶胀行为的高质子传导聚合物电解质膜。
ACS Appl Mater Interfaces. 2018 Jan 10;10(1):1173-1186. doi: 10.1021/acsami.7b13542. Epub 2017 Dec 19.
4
Hydrocarbon-Based Polymer Electrolyte Membranes: Importance of Morphology on Ion Transport and Membrane Stability.基于碳氢化合物的聚合物电解质膜：形态对离子传输和膜稳定性的重要性。
Chem Rev. 2017 Mar 22;117(6):4759-4805. doi: 10.1021/acs.chemrev.6b00586. Epub 2017 Mar 3.
5
New Insights into Perfluorinated Sulfonic-Acid Ionomers.全氟磺酸离子聚合物的新见解。
Chem Rev. 2017 Feb 8;117(3):987-1104. doi: 10.1021/acs.chemrev.6b00159. Epub 2017 Jan 23.
6
Recent development of polymer electrolyte membranes for fuel cells.用于燃料电池的聚合物电解质膜的最新进展。
Chem Rev. 2012 May 9;112(5):2780-832. doi: 10.1021/cr200035s. Epub 2012 Feb 16.
7
Alternative polymer systems for proton exchange membranes (PEMs).用于质子交换膜（PEMs）的替代聚合物体系。
Chem Rev. 2004 Oct;104(10):4587-611. doi: 10.1021/cr020711a.