• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

掺铒氧氟磷酸盐玻璃的成核与生长行为

Nucleation and growth behavior of Er doped oxyfluorophosphate glasses.

作者信息

Ojha N, Szczodra A, Boetti N G, Massera J, Petit L

机构信息

Photonics Laboratory, Tampere University Korkeakoulunkatu 3 FI-33720 Tampere Finland

Fondazione LINKS - Leading Innovation & Knowledge for Society Via P. C. Boggio 61 10138 Torino Italy.

出版信息

RSC Adv. 2020 Jul 7;10(43):25703-25716. doi: 10.1039/d0ra04681g. eCollection 2020 Jul 3.

DOI:10.1039/d0ra04681g
PMID:35518613
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9055356/
Abstract

The nucleation and growth behavior of glasses with the composition (75 NaPO-25 CaF) -(TiO/ZnO/MgO) , with = 0 and = 1.5 (in mol%) is investigated. The glasses possess similar activation energy for crystallization and Johnson-Mehl-Avrami exponent, with value 2 confirming bulk crystallization of crystals with needle like shape. The Ti and Mg glasses exhibit broader nucleation curve and higher than the = 0 and Zn glasses due to their stronger field strength. The crystal growth rates were determined and validated using SEM. Finally, we showed that the nucleation and growth of glasses can be controlled due to the large difference between onset of crystallization and maximum nucleation temperature which is crucial when preparing novel transparent glass-ceramics.

摘要

研究了组成为(75NaPO - 25CaF)-(TiO/ZnO/MgO)、x = 0和x = 1.5（摩尔%）的玻璃的成核和生长行为。这些玻璃具有相似的结晶活化能和约翰逊-梅尔-阿夫拉米指数，其值为2证实了针状晶体的体结晶。由于Ti和Mg玻璃具有更强的场强，它们比x = 0的玻璃和Zn玻璃表现出更宽的成核曲线和更高的G值。使用扫描电子显微镜确定并验证了晶体生长速率。最后，我们表明，由于结晶起始温度和最大成核温度之间的巨大差异，玻璃的成核和生长是可以控制的，这在制备新型透明玻璃陶瓷时至关重要。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/fbd0abcd938a/d0ra04681g-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/2e66e36fef2d/d0ra04681g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/468ac01c046e/d0ra04681g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/c0faba01827f/d0ra04681g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/88328d34c157/d0ra04681g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/335047cc0297/d0ra04681g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/32e9865b5cbe/d0ra04681g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/88725cb8ef54/d0ra04681g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/a3c55be792c2/d0ra04681g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/bc2572dbe1f6/d0ra04681g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/d8528fe71745/d0ra04681g-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/cf0ab475f278/d0ra04681g-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/dd47e1f1f3cc/d0ra04681g-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/fbd0abcd938a/d0ra04681g-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/2e66e36fef2d/d0ra04681g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/468ac01c046e/d0ra04681g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/c0faba01827f/d0ra04681g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/88328d34c157/d0ra04681g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/335047cc0297/d0ra04681g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/32e9865b5cbe/d0ra04681g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/88725cb8ef54/d0ra04681g-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/a3c55be792c2/d0ra04681g-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/bc2572dbe1f6/d0ra04681g-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/d8528fe71745/d0ra04681g-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/cf0ab475f278/d0ra04681g-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/dd47e1f1f3cc/d0ra04681g-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3cc/9055356/fbd0abcd938a/d0ra04681g-f13.jpg

相似文献

1
Nucleation and growth behavior of Er doped oxyfluorophosphate glasses.掺铒氧氟磷酸盐玻璃的成核与生长行为
RSC Adv. 2020 Jul 7;10(43):25703-25716. doi: 10.1039/d0ra04681g. eCollection 2020 Jul 3.
2
Phosphate/oxyfluorophosphate glass crystallization and its impact on dissolution and cytotoxicity.磷酸盐/氧氟磷酸盐玻璃的析晶及其对溶解和细胞毒性的影响。
Mater Sci Eng C Mater Biol Appl. 2020 Dec;117:111269. doi: 10.1016/j.msec.2020.111269. Epub 2020 Jul 6.
3
Effect of Partial Crystallization on the Structural and Luminescence Properties of Er-Doped Phosphate Glasses.部分结晶对掺铒磷酸盐玻璃结构和发光性能的影响。
Materials (Basel). 2017 Apr 28;10(5):473. doi: 10.3390/ma10050473.
4
Non-Isothermal Kinetic Analysis of the Crystallization of Metallic Glasses Using the Master Curve Method.用主曲线法对金属玻璃结晶进行非等温动力学分析
Materials (Basel). 2011 Dec 20;4(12):2231-2243. doi: 10.3390/ma4122231.
5
The effect of MgO/TiO on structural and crystallization behavior of near invert phosphate-based glasses.MgO/TiO 对近反转磷酸盐基玻璃结构和结晶行为的影响。
J Biomed Mater Res B Appl Biomater. 2020 Apr;108(3):674-686. doi: 10.1002/jbm.b.34421. Epub 2019 Jun 7.
6
Isokinetic Analysis of FeCoCrMoYCB Bulk Metallic Glass: Effect of Minor Copper Addition.FeCoCrMoYCB块体金属玻璃的等速动力学分析：微量添加铜的影响。
Materials (Basel). 2020 Aug 21;13(17):3704. doi: 10.3390/ma13173704.
7
On the development of two characteristically different crystal morphology in SiO(2)-MgO-Al (2)O (3)-K (2)O-B (2)O (3)-F glass-ceramic system.关于SiO(2)-MgO-Al (2)O (3)-K (2)O-B (2)O (3)-F微晶玻璃系统中两种特征不同的晶体形态的发展
J Mater Sci Mater Med. 2009 Jan;20(1):51-66. doi: 10.1007/s10856-008-3536-9. Epub 2008 Aug 14.
8
Crystallization Kinetics Analysis of the Amorphouse MgZnCa Alloy at the Isothermal Annealing Temperature of 507 K.非晶态MgZnCa合金在507K等温退火温度下的结晶动力学分析
Materials (Basel). 2020 Jun 23;13(12):2815. doi: 10.3390/ma13122815.
9
Crystallization kinetics of lithium niobate glass: determination of the Johnson-Mehl-Avrami-Kolmogorov parameters.铌酸锂玻璃的结晶动力学：约翰逊-梅勒-阿弗拉米-科尔莫戈罗夫参数的确定。
Phys Chem Chem Phys. 2013 Jun 28;15(24):9940-6. doi: 10.1039/c3cp50909e. Epub 2013 May 15.
10
Crystallization kinetics of orthorhombic paracetamol from supercooled melts studied by non-isothermal DSC.通过非等温差示扫描量热法研究过冷熔体中正交晶型扑热息痛的结晶动力学。
Drug Dev Ind Pharm. 2017 Feb;43(2):257-263. doi: 10.1080/03639045.2016.1236810. Epub 2016 Oct 2.

引用本文的文献

1
Crystallization Mechanism and Optical Properties of Antimony-Germanate-Silicate Glass-Ceramic Doped with Europium Ions.掺铕离子的锑锗硅酸盐微晶玻璃的析晶机制与光学性能
Materials (Basel). 2022 May 26;15(11):3797. doi: 10.3390/ma15113797.

本文引用的文献

1
The effect of MgO/TiO on structural and crystallization behavior of near invert phosphate-based glasses.MgO/TiO 对近反转磷酸盐基玻璃结构和结晶行为的影响。
J Biomed Mater Res B Appl Biomater. 2020 Apr;108(3):674-686. doi: 10.1002/jbm.b.34421. Epub 2019 Jun 7.
2
Structural characterization and physical properties of P2O5-CaO-Na2O-TiO2 glasses by Fourier transform infrared, Raman and solid-state magic angle spinning nuclear magnetic resonance spectroscopies.采用傅里叶变换红外、拉曼和固态魔角旋转核磁共振光谱对 P2O5-CaO-Na2O-TiO2 玻璃的结构特征和物理性能进行了研究。
Acta Biomater. 2012 Jan;8(1):333-40. doi: 10.1016/j.actbio.2011.08.025. Epub 2011 Aug 31.
3
The Scherrer equation versus the 'Debye-Scherrer equation'.
谢乐方程与“德拜-谢乐方程”
Nat Nanotechnol. 2011 Aug 28;6(9):534. doi: 10.1038/nnano.2011.145.
4
Nucleation.成核作用
Cryst Growth Des. 2010 Nov 15;10(12):5007-5019. doi: 10.1021/cg1011633.
5
Upconversion and anti-Stokes processes with f and d ions in solids.固体中f离子和d离子的上转换及反斯托克斯过程。
Chem Rev. 2004 Jan;104(1):139-73. doi: 10.1021/cr020357g.