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工业生物质循环流化床锅炉燃烧高碱氯燃料时积灰动态过程的研究

Investigation of ash deposition dynamic process in an industrial biomass CFB boiler burning high alkali and chlorine fuel.

作者信息

Zhang Hengli, Yu Chunjiang, Luo Zhongyang

机构信息

State Key Laboratory of Clean Energy Utilization, Zhejiang University Hangzhou 310027 China

出版信息

RSC Adv. 2020 Jun 4;10(36):21420-21426. doi: 10.1039/d0ra04370b. eCollection 2020 Jun 2.

Abstract

Biomass direct combustion for power generation is used widely in China. The circulating fluidized bed (CFB) boiler has a lower combustion temperature and a wide fuel adaptability, which is suitable for biomass combustion. The dynamic process of ash deposition in a CFB boiler is different from that in a grate furnace because it has a lower combustion temperature and a higher flue gas flow. In this work, the dynamic process of ash deposition on a superheater in a 50 MW biomass CFB boiler was studied by a deposit sampling system at different deposition times. Multiple deposit samples with different deposition times were observed and analysed to obtain an indication of deposit changes with time to understand the entire deposit build-up process. This study differs from previous studies on ash deposition and the deposition process could be identified as occurring in three stages: (1) initial deposition, (2) KCI deposition and (3) capturing of fly ash particles. In the first stage, the temperature gradient near the superheater led to the deposition of fine particles smaller than 2 μm from the flue gas through thermophoretic deposition. In the second stage, the surface became rough, which led to an increase in gas-phase KCl condensation rate and the formation of a dense and continuous KCl layer after the initial deposition. In the third stage, KCI provided a sticky layer to capture larger particles in the flue gas. Thus, more large particles were captured in the flue gas and the KCl continued to condense. As the surface temperature was increased, the condensation rate of the gas-phase KCl decreased. The higher surface temperature enhanced KCI melting and captured more fly ash particles, which led to a rapid build-up of ash deposits on the heating surfaces.

摘要

生物质直接燃烧发电在中国得到广泛应用。循环流化床(CFB)锅炉燃烧温度较低,燃料适应性广,适合生物质燃烧。CFB锅炉中灰分沉积的动态过程与层燃炉不同,因为其燃烧温度较低且烟气流速较高。在这项工作中,通过沉积物采样系统研究了一台50MW生物质CFB锅炉过热器上不同沉积时间的灰分沉积动态过程。观察并分析了不同沉积时间的多个沉积物样本,以获得沉积物随时间的变化情况,从而了解整个沉积物形成过程。本研究与以往关于灰分沉积的研究不同,沉积过程可分为三个阶段:(1)初始沉积,(2)KCl沉积,(3)飞灰颗粒捕获。在第一阶段,过热器附近的温度梯度导致小于2μm的细颗粒通过热泳沉积从烟气中沉积下来。在第二阶段,表面变得粗糙,这导致气相KCl凝结速率增加,并在初始沉积后形成致密连续的KCl层。在第三阶段,KCl提供了一个粘性层来捕获烟气中的较大颗粒。因此,烟气中捕获了更多的大颗粒,KCl继续凝结。随着表面温度升高,气相KCl的凝结速率降低。较高的表面温度增强了KCl的熔化,并捕获了更多的飞灰颗粒,导致受热面上的灰分沉积物迅速堆积。

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