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一种新型富氧含能盐二肼四硝基乙烷:一种具有高密度和良好性能的有前景的炸药替代品。

A new oxygen-rich energetic salt dihydrazine tetranitroethide: a promising explosive alternative with high density and good performance.

作者信息

Mei Haozheng, Yang Junqing, Cao Wenli, Hu Yong, He Piao, Zhang Jian-Guo

机构信息

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology Beijing 100081 P. R. China

College of Chemistry and Chemical Engineering, Central South University Changsha 410083 Hunan P. R. China.

出版信息

RSC Adv. 2020 Jun 17;10(39):23250-23253. doi: 10.1039/d0ra04167j. eCollection 2020 Jun 16.

Abstract

A novel high-energy salt with good oxygen balance, dihydrazine tetranitroethide (5), has been synthesized and characterized by FT-IR spectroscopy, NMR spectroscopy, elemental analysis, and X-ray single crystal diffraction. Compound 5 exhibits high crystal density (1.81 g cm) and impressive detonation velocity (9508 m s) and detonation pressure (37.9 GPa), showing potential applications as a high performance explosive and a promising additive of propellants.

摘要

一种具有良好氧平衡的新型高能盐——四硝基乙二酸二肼(5)已被合成,并通过傅里叶变换红外光谱、核磁共振光谱、元素分析和X射线单晶衍射进行了表征。化合物5具有高晶体密度(1.81 g/cm³)以及令人印象深刻的爆速(9508 m/s)和爆压(37.9 GPa),显示出作为高性能炸药和有前景的推进剂添加剂的潜在应用。

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