四,五-双(二硝基甲基)呋咱基氧化钾：正氧平衡的绿色单质炸药。
Potassium 4,5-Bis(dinitromethyl)furoxanate: A Green Primary Explosive with a Positive Oxygen Balance.
机构信息
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA).
出版信息
Angew Chem Int Ed Engl. 2016 Jan 11;55(2):772-5. doi: 10.1002/anie.201509209. Epub 2015 Nov 6.
Potassium 4,5-bis(dinitromethyl)furoxanate was synthesized readily from cyanoacetic acid. It was characterized by IR spectroscopy, elemental analysis, NMR spectroscopy, and differential scanning calorimetry (DSC), and the structure was confirmed by X-ray single-crystal diffraction. Its positive oxygen balance, high density (2.130 g cm(-3)), sensitivity (IS=2 J, FS=5 N), and calculated heat of formation (-421.0 kJ mol(-1)), combined with its calculated superior detonation performance (D=7759.0 m s(-1), P=27.3 GPa), make it a competitive replacement as a green primary explosive.
四,5-双(二硝基甲基)呋喃并[3,4-b]吡咯-2,3-二酮钾盐可由氰基乙酸简便合成。通过红外光谱、元素分析、核磁共振波谱和差示扫描量热法（DSC）对其进行了表征，并通过 X 射线单晶衍射对其结构进行了确认。其正氧平衡、高密度（2.130gcm-3）、高感度（IS=2J，FS=5N）和计算生成热（-421.0kJmol-1），结合其计算出的卓越爆轰性能（D=7759.0ms-1，P=27.3GPa），使其成为一种有竞争力的绿色起爆药替代品。
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