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由半层状沸石和微孔有机层交替堆叠组成的新型晶体有机-无机杂化硅酸盐材料。

Novel crystalline organic-inorganic hybrid silicate material composed of the alternate stacking of semi-layered zeolite and microporous organic layers.

作者信息

Yamamoto Katsutoshi, Ikeda Takuji, Tsukamoto Yusuke, Nakaoka Takuma

机构信息

Faculty of Environmental Engineering, The University of Kitakyushu 1-1 Hibikino, Wakamatsu-ku Kitakyushu 808-0135 Japan

Research Center for Compact Chemical System, National Institute of Advanced Science and Technology 4-2-1 Nigatake, Miyagino-ku Sendai 983-8551 Japan

出版信息

RSC Adv. 2019 Jan 21;9(5):2641-2644. doi: 10.1039/c8ra09908a. eCollection 2019 Jan 18.

DOI:10.1039/c8ra09908a
PMID:35520522
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9059867/
Abstract

A novel type of crystalline organic-inorganic hybrid microporous silicate material, KCS-5, was synthesized supposedly from a lamellar precursor composed of amphiphilic organosilicic acids. This well-ordered material has a crystalline structure, is thermally stable up to 500 °C and has lipophilic 1-dimensional micropores.

摘要

一种新型的晶体有机-无机杂化微孔硅酸盐材料KCS-5,据推测是由两亲性有机硅酸组成的层状前驱体合成的。这种有序材料具有晶体结构,在高达500°C的温度下热稳定,并且具有亲脂性一维微孔。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/3d047853e562/c8ra09908a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/3c1afea4d4bf/c8ra09908a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/759c3a1a2f95/c8ra09908a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/42db926eb8ac/c8ra09908a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/34d006f43096/c8ra09908a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/3d047853e562/c8ra09908a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/3c1afea4d4bf/c8ra09908a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/759c3a1a2f95/c8ra09908a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/42db926eb8ac/c8ra09908a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/34d006f43096/c8ra09908a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec9e/9059867/3d047853e562/c8ra09908a-f5.jpg

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本文引用的文献

1
Amphiphilic Organic-Inorganic Hybrid Zeotype Aluminosilicate like a Nanoporous Crystallized Langmuir-Blodgett Film.两亲性有机-无机杂化沸石型硅铝酸盐如纳米多孔结晶的 Langmuir-Blodgett 膜。
Angew Chem Int Ed Engl. 2015 Jun 26;54(27):7994-8. doi: 10.1002/anie.201503661. Epub 2015 May 27.
2
A highly crystalline microporous hybrid organic-inorganic aluminosilicate resembling the AFI-type zeolite.一种高度结晶的微孔混合有机-无机铝硅酸盐,类似于 AFI 型沸石。
Chem Commun (Camb). 2012 Jul 28;48(59):7356-8. doi: 10.1039/c2cc33417h. Epub 2012 Jun 20.
3
ECS-3: a crystalline hybrid organic-inorganic aluminosilicate with open porosity.
ECS - 3:一种具有开放孔隙率的结晶性有机 - 无机铝硅酸盐杂化物。
Angew Chem Int Ed Engl. 2012 Jan 16;51(3):666-9. doi: 10.1002/anie.201105496. Epub 2011 Nov 30.
4
Synthesis and crystal structure of a layered silicate HUS-1 with a halved sodalite-cage topology.层状硅酸盐 HUS-1 的合成与晶体结构,其拓扑结构为减半的方钠石笼。
Inorg Chem. 2011 Mar 21;50(6):2294-301. doi: 10.1021/ic1020065. Epub 2011 Feb 4.
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Organic-inorganic hybrid zeolites containing organic frameworks.含有有机骨架的有机-无机杂化沸石
Science. 2003 Apr 18;300(5618):470-2. doi: 10.1126/science.1081019.
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An ordered mesoporous organosilica hybrid material with a crystal-like wall structure.一种具有类晶体壁结构的有序介孔有机硅杂化材料。
Nature. 2002 Mar 21;416(6878):304-7. doi: 10.1038/416304a.