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一种使用工程化水纳米结构去除纺织品气味的新方法。

A novel method for textile odor removal using engineered water nanostructures.

作者信息

Zhu Lisha, Liu Yanbiao, Ding Xuemei, Wu Xiongying, Sand Wolfgang, Zhou Huiling

机构信息

Fashion Institute, Donghua University Shanghai 200051 P. R. China

Shanghai International Institute of Design & Innovation Shanghai 200080 P. R. China.

出版信息

RSC Adv. 2019 Jun 5;9(31):17726-17736. doi: 10.1039/c9ra01988j. eCollection 2019 Jun 4.

Abstract

The malodor attached to textiles not only causes indoor environmental pollution but also endangers people's health even at low concentrations. Existing technologies cannot effectively eliminate the odor. Herein, an effective and environmentally friendly technology was proposed to address this challenging issue. This technology utilizes electrospraying process to produce Engineered Water Nanostructures (EWNS) in a controllable manner. Upon application of a high voltage to the Taylor cone, EWNS can be generated from the condensed vapor water through a Peltier element. Smoking, cooking and perspiration, considered the typical indoor malodorous gases emitted from human activities, were studied in this paper. A headspace SPME method in conjunction with GC-MS was employed for the extraction, detection and quantification of any odor residues. Results indicated that EWNS played a significant role in the deodorization process with removal efficiencies for the three odors were 95.3 ± 0.1%, 100.0 ± 0.0% and 43.7 ± 2.3%, respectively. The Reactive Oxygen Species (ROS) contained in the EWNS, mainly hydroxyl (OH˙) and superoxide radicals are the possible mechanisms for the odor removal. These ROS are strong oxidative and highly reactive and have the ability to convert odorous compounds to non-odorous compounds through various chemical reaction mechanisms. This study showed clearly the potential of the proposed method in the field of odor removal and can be applied in the battle against indoor air pollution.

摘要

附着在纺织品上的恶臭不仅会造成室内环境污染,而且即使在低浓度下也会危害人体健康。现有技术无法有效消除这种气味。在此,我们提出了一种有效且环保的技术来解决这一具有挑战性的问题。该技术利用电喷雾工艺以可控方式生产工程水纳米结构(EWNS)。在泰勒锥上施加高电压后,EWNS可通过珀耳帖元件由冷凝的水蒸气产生。本文研究了吸烟、烹饪和出汗这三种被认为是人类活动产生的典型室内恶臭气体。采用顶空固相微萃取(SPME)结合气相色谱 - 质谱联用(GC - MS)方法对任何气味残留进行提取、检测和定量。结果表明,EWNS在除臭过程中发挥了重要作用,对这三种气味的去除效率分别为95.3±0.1%、100.0±0.0%和43.7±2.3%。EWNS中含有的活性氧物种(ROS),主要是羟基(OH˙)和超氧自由基,是除臭的可能机制。这些ROS具有强氧化性和高反应活性,能够通过各种化学反应机制将有气味的化合物转化为无气味的化合物。这项研究清楚地表明了所提出方法在除臭领域的潜力,可应用于对抗室内空气污染的斗争中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7fcf/9064573/a42e880b5390/c9ra01988j-f1.jpg

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