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用于锂离子电池的LiTiO-焦炭复合负极材料的研究。

An investigation of LiTiO-coke composite anode material for Li-ion batteries.

作者信息

Liu Youlin, Li Wensheng, Zhou Xiaoping

机构信息

Department of Chemical Engineering, Hunan University Changsha Hunan 410082 PR China

出版信息

RSC Adv. 2019 Jun 5;9(31):17835-17840. doi: 10.1039/c9ra02611h. eCollection 2019 Jun 4.

DOI:10.1039/c9ra02611h
PMID:35520566
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9064618/
Abstract

Anode material LiTiO-coke was prepared and tested for lithium-ion batteries. The as-prepared material exhibits excellent cycling stability and outstanding rate performance. Charge/discharge capacities of 266 mA h g at 0.100 A g and 200 mA h g at 1.000 A g are reached for LiTiO-coke. A cycling life-time test shows that LiTiO-coke gives a specific capacity of 264 mA h g at 0.300 A g and a capacity retention of 92% after 1000 cycles of charge/discharge.

摘要

制备了阳极材料LiTiO-焦炭,并对其进行了锂离子电池测试。所制备的材料表现出优异的循环稳定性和出色的倍率性能。LiTiO-焦炭在0.100 A g时的充/放电容量达到266 mA h/g,在1.000 A g时达到200 mA h/g。循环寿命测试表明,LiTiO-焦炭在0.300 A g时的比容量为264 mA h/g,在1000次充/放电循环后的容量保持率为92%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/cd9fe40742f3/c9ra02611h-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/f5e3a9f627ea/c9ra02611h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/24d29ecc9ffc/c9ra02611h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/7cb960f4b690/c9ra02611h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/4e0947ca349d/c9ra02611h-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/cd9fe40742f3/c9ra02611h-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/f5e3a9f627ea/c9ra02611h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/24d29ecc9ffc/c9ra02611h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/7cb960f4b690/c9ra02611h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/4e0947ca349d/c9ra02611h-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7895/9064618/cd9fe40742f3/c9ra02611h-f5.jpg

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本文引用的文献

1
Porous Li4 Ti5 O12 coated with N-doped carbon from ionic liquids for Li-ion batteries.用于锂离子电池的、由离子液体包覆氮掺杂碳的多孔Li4Ti5O12。
Adv Mater. 2011 Mar 18;23(11):1385-8. doi: 10.1002/adma.201003294. Epub 2011 Feb 2.
2
In situ synthesis of high-loading Li4Ti5O12-graphene hybrid nanostructures for high rate lithium ion batteries.原位合成高负载量 Li4Ti5O12-石墨烯杂化纳米结构用于高速率锂离子电池。
Nanoscale. 2011 Feb;3(2):572-4. doi: 10.1039/c0nr00639d. Epub 2010 Nov 12.
3
Li-ion diffusion in the equilibrium nanomorphology of spinel Li(4+x)Ti(5)O(12).
锂离子在尖晶石Li(4+x)Ti(5)O(12)平衡纳米形态中的扩散
J Phys Chem B. 2009 Jan 8;113(1):224-30. doi: 10.1021/jp8073706.