Chen Ling, Liu Debao, Yang Ping
School of Material Science and Engineering, University of Jinan Jinan 250022 P. R. China
RSC Adv. 2019 Apr 25;9(23):12793-12800. doi: 10.1039/c9ra01928f.
Reduced graphene oxide (rGO) integrated with iron oxide nanoparticles (α-FeO/rGO) composites with different morphologies were successfully obtained through the synthesis and mechanical agitation methods. It was found that the α-FeO was densely and freely dispersed on the rGO layer. By comparing electrochemical properties, the sheet-like α-FeO/rGO composites demonstrate excellent electrochemical performance: the highest specific capacitance, and excellent cycling stability and rate capacity. The specific capacitance is 970 F g at a current density of 1 A g and the capacitance retention is 75% after 2000 cycles with the current density reaching 5 A g. It is mainly due to the synergistic effect between the α-FeO and rGO, and the high conductivity of the rGO offers a fast channel for the movement of electrons.
通过合成和机械搅拌方法成功制备了具有不同形貌的还原氧化石墨烯(rGO)与氧化铁纳米颗粒(α-FeO/rGO)的复合材料。发现α-FeO密集且自由地分散在rGO层上。通过比较电化学性能,片状α-FeO/rGO复合材料表现出优异的电化学性能:最高比电容、出色的循环稳定性和倍率性能。在1 A g的电流密度下比电容为970 F g,在电流密度达到5 A g的情况下经过2000次循环后电容保持率为75%。这主要归因于α-FeO与rGO之间的协同效应,并且rGO的高电导率为电子移动提供了快速通道。