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一种孔口设计:将水注入C中。

An orifice design: water insertion into C.

作者信息

Hashikawa Yoshifumi, Kizaki Kazuro, Hirose Takashi, Murata Yasujiro

机构信息

Institute for Chemical Research, Kyoto University Uji Kyoto 611-0011 Japan

出版信息

RSC Adv. 2020 Nov 6;10(66):40406-40410. doi: 10.1039/d0ra09067k. eCollection 2020 Nov 2.

DOI:10.1039/d0ra09067k
PMID:35520847
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9057476/
Abstract

Using an open-cage C derivative possessing an orifice designed on the basis of computational studies, we have experimentally demonstrated the quantitative encapsulation of HO as well as effective conversion into HO@C in an overall yield remarkably higher than the previously reported methods by 2-5 times.

摘要

使用一种基于计算研究设计的具有孔口的开孔碳衍生物,我们通过实验证明了过氧化氢(HO)的定量封装以及有效地转化为碳包裹过氧化氢(HO@C),其总产率比之前报道的方法显著高出2至5倍。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/146d128a391c/d0ra09067k-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/9c8d44a3bb81/d0ra09067k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/62902d34f7ff/d0ra09067k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/146d128a391c/d0ra09067k-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/9c8d44a3bb81/d0ra09067k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/62902d34f7ff/d0ra09067k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63a9/9057476/146d128a391c/d0ra09067k-s1.jpg

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本文引用的文献

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Commun Chem. 2020 Jul 21;3(1):90. doi: 10.1038/s42004-020-00340-x.
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Synthesis of Ar@C using molecular surgery.利用分子手术合成 Ar@C
Chem Commun (Camb). 2020 Sep 10;56(72):10521-10524. doi: 10.1039/d0cc04201c.
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First Synthesis and Characterization of CH @C.CH@C的首次合成与表征。
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Probing the interaction between the encapsulated water molecule and the fullerene cages in HO@C and HO@CN.探究HO@C和HO@CN中被包裹水分子与富勒烯笼之间的相互作用。
Chem Sci. 2018 Jun 4;9(25):5666-5671. doi: 10.1039/c8sc01031e. eCollection 2018 Jul 7.
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Lithium-Ion Endohedral Fullerene (Li @C ) Dopants in Stable Perovskite Solar Cells Induce Instant Doping and Anti-Oxidation.稳定的钙钛矿太阳能电池中的锂离子内嵌富勒烯(Li@C)掺杂剂可诱导即时掺杂和抗氧化作用。
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Gadolinium based endohedral metallofullerene Gd@CN as a relaxation boosting agent for dissolution DNP at high fields.基于钆的内嵌金属富勒烯Gd@CN作为高场下促进溶解动态核极化的弛豫增强剂。
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Facile Access to Azafullerenyl Cation CN and Specific Interaction with Entrapped Molecules.易于获得全氮富勒烯阳离子 CN 并与被捕获分子的特异性相互作用。
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