Dennison Genevieve H, Curty Christophe, Metherell Alexander J, Micich Eva, Zaugg Andreas, Ward Michael D
Land Division, Defence Science and Technology Group Fishermans Bend Melbourne Australia
Organic Chemistry Branch, Federal Office for Civil Protection (FOCP), Spiez Laboratory Spiez Switzerland.
RSC Adv. 2019 Mar 6;9(14):7615-7619. doi: 10.1039/c9ra00824a.
The addition of G- and V-series organophosphorus chemical warfare agents and simulants to a paper-based assay of a dual-luminescent Ir(iii)/Eu(iii) dyad generated different emissive responses between the classes and compound types. The emission responses are complex and based not only on altering the balance between red Eu(iii)-based and blue Ir(iii)-based luminescent components, but also incorporate other factors such as analyte volatility, concentration and UV absorption. The extent of this emission colour change was analysed colorimetrically and related to the change in RGB output over time.
在基于纸张的双发光铱（III）/铕（III）二元体系分析中添加G系列和V系列有机磷化学战剂及其模拟物，会在不同类别和化合物类型之间产生不同的发射响应。发射响应很复杂，不仅基于改变基于红色铕（III）和蓝色铱（III）的发光成分之间的平衡，还涉及其他因素，如分析物的挥发性、浓度和紫外线吸收。通过比色法分析这种发射颜色变化的程度，并将其与RGB输出随时间的变化相关联。
