Inaba Ryoto, Oka Kouki, Iwami Takahiro, Miyake Yusuke, Tajima Kunihiko, Imoto Hiroaki, Naka Kensuke
Faculty of Molecular Chemistry and Engineering, Graduate School of Science and Technology, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
Center for Future Innovation (CFI) and Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Inorg Chem. 2022 May 16;61(19):7318-7326. doi: 10.1021/acs.inorgchem.2c00158. Epub 2022 May 6.
Heteroatom-fused π-conjugated molecules have attracted considerable attention, and various elements for such fusion have been investigated. Herein, we focused on pnictogen-fused heterofluorenes. The structures, reactivity with O and I, coordination ability to AuCl, and photophysical properties were systematically studied to better understand the effects of pnictogen atoms on the nature of π-conjugated molecules.
杂原子稠合的π共轭分子已引起了广泛关注，并且已经研究了用于这种稠合的各种元素。在此，我们重点研究了氮族元素稠合的杂芴。系统地研究了它们的结构、与O和I的反应性、对AuCl的配位能力以及光物理性质，以更好地理解氮族元素原子对π共轭分子性质的影响。
