1,3,5-三[(2-四唑-5-基)甲基]异氰脲酸酯及其三阳离子盐作为热稳定且钝感的含能材料
1,3,5-Tris[(2-tetrazol-5-yl)methyl]isocyanurate and Its Tricationic Salts as Thermostable and Insensitive Energetic Materials.
作者信息
Kumar Parasar, Ghule Vikas D, Dharavath Srinivas
机构信息
Energetic Materials Laboratory, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, Uttar Pradesh, India.
Department of Chemistry, National Institute of Technology Kurukshetra, Kurukshetra 136119, Haryana, India.
出版信息
Org Lett. 2022 May 20;24(19):3555-3559. doi: 10.1021/acs.orglett.2c01225. Epub 2022 May 6.
Various energetic salts () were obtained from 1,3,5-tris[(2-tetrazol-5-yl)methyl]isocyanurate (), while N2,N4,N6-tri(1-tetrazol-5-yl)-1,3,5-triazine-2,4,6-triamine () and ,'-{6-[(1-tetrazol-5-yl)amino]-1,3,5-triazine-2,4-diyl}bis[-(1-tetrazol-5-yl)nitramide] () were obtained from cyanuric chloride via a simple, efficient two-step synthetic route from inexpensive starting materials. Compounds and show excellent detonation properties (VOD = 7876-8832 m s, and DP = 20.73-30.0 GPa), a high nitrogen content (>62%), and high positive heats of formation (205.2-1888.9 kJ mol) with excellent thermostability and remarkable insensitivity.
多种含能盐（）由1,3,5-三[(2-四唑-5-基)甲基]异氰尿酸酯（）制得，而N2,N4,N6-三(1-四唑-5-基)-1,3,5-三嗪-2,4,6-三胺（）和,'-{6-[(1-四唑-5-基)氨基]-1,3,5-三嗪-2,4-二基}双[-(1-四唑-5-基)硝酰胺]（）则由三聚氯氰通过一条简单、高效的两步合成路线，以廉价原料制得。化合物 和 表现出优异的爆轰性能（爆速 = 7876 - 8832 m s，爆压 = 20.73 - 30.0 GPa）、高氮含量（>62%）以及高正生成热（205.2 - 1888.9 kJ mol），具有出色的热稳定性和显著的钝感度。
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