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掀起波澜:废水处理的重大变革——热力学如何支持资源回收和再利用。

Making Waves: A sea change in treating wastewater - Why thermodynamics supports resource recovery and recycling.

机构信息

Sino-Dutch R&D Centre for Future Wastewater Treatment Technologies/Key Laboratory of Urban Stormwater System and Water Environment, Beijing University of Civil Engineering and Architecture, Beijing 100044, China.

Sino-Dutch R&D Centre for Future Wastewater Treatment Technologies/Key Laboratory of Urban Stormwater System and Water Environment, Beijing University of Civil Engineering and Architecture, Beijing 100044, China.

出版信息

Water Res. 2022 Jun 30;218:118516. doi: 10.1016/j.watres.2022.118516. Epub 2022 Apr 29.

Abstract

Entropy is a concept defined by the second law of thermodynamics. Applying this concept to the world we live in, entropy production must be minimized and negentropy (negative entropy production) should be accelerated, in order to produce a healthy and stable ecological system. The present wastewater treatment, however, contributes to entropy production. This means that conventional wastewater treatment, without recovery of resource and energy, will gradually but inevitably contribute to a deteriorating ecological balance. When the self-cleaning ability of the natural ecological system is limited, the need to develop sustainable wastewater treatment in order to delay entropy production and accelerate negentropy becomes urgent. Resource and energy recovery from wastewater should be the first priority, as they can contribute significantly towards minimizing entropy production and accelerating negentropy. Sustainable wastewater treatment must focus on recovering recyclable high value-added organic chemicals from wastewater and/or excess sludge to minimize entropy production caused by methane (CH, once combusted, is converted into CO - an even higher substance in entropy) via anaerobic digestion. Instead of CH, thermal energy present in the effluent can be utilized for heating/cooling buildings and also for drying excess sludge towards incineration to recover more energy. Overall, this can lead to a carbon-neutral operation and even creating a "carbon sink" could be possible for wastewater treatment.

摘要

熵是由热力学第二定律定义的概念。将这个概念应用于我们生活的世界,为了产生一个健康稳定的生态系统,熵产生必须最小化,负熵(负熵产生)应该加速。然而,目前的废水处理却导致了熵的产生。这意味着,如果没有资源和能源的回收,传统的废水处理将逐渐但不可避免地导致生态平衡恶化。当自然生态系统的自我清洁能力有限时,为了延迟熵的产生并加速负熵,开发可持续的废水处理就变得紧迫。从废水中回收资源和能源应该是当务之急,因为它们可以极大地有助于最小化熵的产生和加速负熵。可持续的废水处理必须专注于从废水中回收可回收的高附加值有机化学品,以及/或者通过厌氧消化从剩余污泥中回收可回收的高附加值有机化学品,以最小化甲烷(CH)引起的熵产生(一旦燃烧,CH 会转化为 CO,CO 的熵更高)。废水中的热能可以代替 CH 用于建筑物的加热/冷却,也可以用于干燥剩余的污泥以便焚烧,以回收更多的能量。总的来说,这可以实现碳中性运行,甚至有可能为废水处理创造“碳汇”。

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