Liu Lei, Zhang Lei, Wen Wei, Jiao Jiao, Cheng Hongbing, Ma Xin, Sun Chang
State Key Laboratory of Severe Weather and Key Laboratory of Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences, Beijing, 100081, China.
School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
Environ Geochem Health. 2023 May;45(5):1537-1553. doi: 10.1007/s10653-022-01275-z. Epub 2022 May 8.
Air pollution poses a serious threat to human health. The implementation of air pollution prevention and control policies has gradually reduced the level of atmospheric fine particles in Beijing. Exploring the latest characteristics of PM has become the key to further improving pollution reduction measures. In the current study, outdoor PM samples were collected in the spring and summer of Beijing, and the chemical species, oxidative potential (OP), and sources of PM were characterized. The mean PM concentration during the entire study period was 41.6 ± 30.9 μg m. Although the PM level in summer was lower, its OP level was significantly higher than that in spring. SO, NH, EC, NO, and OC correlated well with volume-normalized OP (OP). Strong positive correlations were found between OP and the following elements: Cu, Pb, Zn, Ni, As, Cr, Sn, Cd, Al, and Mn. Seven sources of PM were identified, including traffic, soil dust, secondary sulfate, coal and biomass burning, oil combustion, secondary nitrate, and industry. Multiple regression analysis indicated that coal and biomass combustion, industry, and traffic were the main contributors to the OP in spring, while secondary sulfate, oil combustion, and industry played a leading role in summer. The source region analysis revealed that different pollution sources were related to specific geographic distributions. In addition to local emission reduction policies, multi-provincial cooperation is necessary to further improve Beijing's air quality and reduce the adverse health effects of PM.
空气污染对人类健康构成严重威胁。空气污染防治政策的实施已使北京大气细颗粒物水平逐步降低。探究颗粒物(PM)的最新特征已成为进一步完善污染减排措施的关键。在本研究中,于北京的春季和夏季采集了室外PM样本,并对PM的化学物种、氧化潜力(OP)及来源进行了表征。整个研究期间PM的平均浓度为41.6±30.9微克/立方米。尽管夏季的PM水平较低,但其OP水平显著高于春季。硫酸根(SO)、铵根(NH)、元素碳(EC)、硝酸根(NO)和有机碳(OC)与体积归一化氧化潜力(OP)相关性良好。在OP与以下元素之间发现了强正相关:铜(Cu)、铅(Pb)、锌(Zn)、镍(Ni)、砷(As)、铬(Cr)、锡(Sn)、镉(Cd)、铝(Al)和锰(Mn)。确定了PM的七个来源,包括交通、土壤扬尘、二次硫酸盐、煤炭和生物质燃烧、燃油燃烧、二次硝酸盐及工业。多元回归分析表明,煤炭和生物质燃烧、工业及交通是春季OP的主要贡献源,而二次硫酸盐、燃油燃烧和工业在夏季起主导作用。源区分析表明,不同污染源与特定的地理分布有关。除了地方减排政策外,还需要多省份合作以进一步改善北京的空气质量并减少PM对健康的不利影响。