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微米级锰作为提高钻井液悬浮能力的加重剂及其作用机理研究

Micro-manganese as a weight agent for improving the suspension capability of drilling fluid and the study of its mechanism.

作者信息

Ma Jingyuan, Yu Peizhi, Xia Boru, An Yuxiu

机构信息

School of Engineering and Technology, China University of Geosciences (Beijing) Haidian District Beijing 100083 China

Key Laboratory of Deep Geo Drilling Technology, Ministry of Land and Resources Beijing 100083 China.

出版信息

RSC Adv. 2019 Nov 1;9(61):35509-35523. doi: 10.1039/c9ra07283g. eCollection 2019 Oct 31.

Abstract

The contradiction between the sag stability of weighted materials and the rheological properties of drilling fluids is one of the main technical difficulties in high-density drilling fluids. Thus, understanding the suspension mechanism of weighting materials is the key to improving the sag stability of weighting materials. In this study, micro-manganese (MnO) was compared with the commonly used weighting agent barite to study the suspension mechanism of MnO. The weighting effect of MnO and barite was evaluated by static and dynamic sag tests, rheological property measurements and filtration property tests. The evaluation experiment results showed that the sag stability of MnO was better than that of barite, and MnO could significantly increase the suspension capacity of drilling fluids and improve their rheology property. The scanning electron microscopy (SEM) and other test results indicate that the small and uniform spherical structure of micro-manganese not only causes it to have less friction, but also intense Brownian motion in drilling fluid, which weakens the sag caused by gravity. The large specific surface area of MnO results in the strong adsorption of water molecules and polymers in drilling fluids, resulting in the formation of a hydrated film on the surface of the MnO particles and physical crosslinking with polymer chains. This prevents sagging caused by the adsorption of small particles to form large particles. The key findings of this work are expected to provide a basis for improving the sag stability of weighting materials in drilling fluids and better the application of micro-manganese in drilling fluids.

摘要

加重材料下沉稳定性与钻井液流变性能之间的矛盾是高密度钻井液中的主要技术难题之一。因此,了解加重材料的悬浮机理是提高加重材料下沉稳定性的关键。在本研究中,将微米级锰(MnO)与常用加重剂重晶石进行比较,以研究MnO的悬浮机理。通过静态和动态下沉试验、流变性能测量和过滤性能测试对MnO和重晶石的加重效果进行了评价。评价实验结果表明,MnO的下沉稳定性优于重晶石,且MnO能显著提高钻井液的悬浮能力并改善其流变性能。扫描电子显微镜(SEM)等测试结果表明,微米级锰的小而均匀的球形结构不仅使其摩擦力较小,而且在钻井液中具有剧烈的布朗运动,这减弱了重力引起的下沉。MnO的大比表面积导致其对钻井液中的水分子和聚合物有强烈的吸附作用,从而在MnO颗粒表面形成水合膜并与聚合物链发生物理交联。这防止了因小颗粒吸附形成大颗粒而导致的下沉。这项工作的关键发现有望为提高钻井液中加重材料的下沉稳定性提供依据,并更好地推动微米级锰在钻井液中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4f1/9074693/e413085713fc/c9ra07283g-f16.jpg

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