刚性[2.2]对环芳烷-卟啉共轭物作为固定距离双金属配合物支架的合成与表征
Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes.
作者信息
Knoll Daniel M, Wiesner Thomas B, Marschner Stefan M, Hassan Zahid, Weis Patrick, Kappes Manfred, Nieger Martin, Bräse Stefan
机构信息
Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT) Fritz-Haber-Weg 6 76131 Karlsruhe Germany
Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT) Fritz-Haber-Weg 2 76131 Karlsruhe Germany.
出版信息
RSC Adv. 2019 Sep 26;9(52):30541-30544. doi: 10.1039/c9ra07055a. eCollection 2019 Sep 23.
This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane-porphyrin conjugates palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal-metal fixed-distance Cu/Zn complexes.
这项工作提出了一种通过钯介导的Stille交叉偶联反应制备单取代和双取代的线性刚性双金属[2.2]对环芳烷-卟啉共轭物的新方法。金属化的卟啉部分可以变化，从而方便地获得模块化的金属-金属固定距离的铜/锌配合物。
Zotero 插件