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用于乙苯选择性氧化的高石墨氮含量介孔碳

Mesoporous carbon with high content of graphitic nitrogen for selective oxidation of ethylbenzene.

作者信息

Wang Jia, Pan Xiaoli, Li Fuwei

机构信息

State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences Lanzhou 730000 PR China

State Key Laboratory of Catalysis, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian 116023 China.

出版信息

RSC Adv. 2019 Sep 9;9(48):28253-28257. doi: 10.1039/c9ra05386g. eCollection 2019 Sep 3.

Abstract

Graphitic-nitrogen doped mesoporous carbon (accounting 85% in all nitrogen species) was easily synthesized by using acetonitrile as a precursor and SBA-15 as a hard template through a chemical vapour deposition method and exhibited a better catalytic performance than other nitrogen-doped carbon materials for selective oxidation of ethylbenzene.

摘要

通过以乙腈为前驱体、SBA - 15为硬模板,采用化学气相沉积法可轻松合成石墨氮掺杂的介孔碳(占所有氮物种的85%),并且在乙苯选择性氧化方面,该材料比其他氮掺杂碳材料表现出更好的催化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef11/9071133/ccb5fb859078/c9ra05386g-f1.jpg

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