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基于碳点的纳米传感器对苋菜红的高选择性和灵敏检测

Highly selective and sensitive detection of amaranth by using carbon dots-based nanosensor.

作者信息

Liu Lizhen, Mi Zhi, Li Haihong, Li Caiqing, Hu Qin, Feng Feng

机构信息

Shanxi Datong University Datong 037009 PR China

School of Chemistry and Materials Science, Shanxi Normal University Linfen 041004 PR China.

出版信息

RSC Adv. 2019 Aug 22;9(45):26315-26320. doi: 10.1039/c9ra04494a. eCollection 2019 Aug 19.

Abstract

In this work, a novel fluorescence nanosensor for selective and sensitive determination of amaranth was constructed using carbon dots (C-dots). Water soluble C-dots with strong fluorescence were obtained by a simple microwave-assisted method using urea and glycine as raw materials. It was found that amaranth can efficiently and sensitively quench the C-dots fluorescence by the inner filter effect (IFE) and non-radiative energy transfer (NRET) mechanisms. The fluorescence quenching efficiency ( /) was strongly correlated with the concentration of amaranth in the 0.2-30 μM range. The detection limit (LOD) is 0.021 μM. There was no significant change in the fluorescence intensity of C-dots when other potentially interfering substances were present in the system. Our C-dots-based nanosensor was successfully utilized for the analysis of amaranth in drinks and showed rapid, sensitive and accurate responses. It indicates that the novel C-dots-based nanosensor has great potential in amaranth detection for real-life applications.

摘要

在本工作中,使用碳点(C点)构建了一种用于选择性和灵敏测定苋菜红的新型荧光纳米传感器。以尿素和甘氨酸为原料,通过简单的微波辅助方法获得了具有强荧光的水溶性C点。研究发现,苋菜红可通过内滤效应(IFE)和非辐射能量转移(NRET)机制有效且灵敏地猝灭C点荧光。在0.2 - 30 μM范围内,荧光猝灭效率( /)与苋菜红浓度密切相关。检测限(LOD)为0.021 μM。当体系中存在其他潜在干扰物质时,C点的荧光强度无显著变化。我们基于C点的纳米传感器成功用于饮料中苋菜红的分析,并表现出快速、灵敏和准确的响应。这表明新型基于C点的纳米传感器在苋菜红的实际检测应用中具有巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b637/9070404/f8b43aa32c68/c9ra04494a-f1.jpg

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