School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, PR China; Shandong Industrial Ceramics Research & Design Institute Co., Ltd., Zibo 255000, PR China.
School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, PR China.
J Colloid Interface Sci. 2022 Sep 15;622:719-727. doi: 10.1016/j.jcis.2022.04.128. Epub 2022 Apr 28.
Excessive conductivity of carbon-based materials led to poor impedance matching, hindering their electromagnetic absorbing application in aerospace and military fields. While, one-dimensional carbon materials are more favorable to build networks, satisfying impedance matching. One-dimensional carbon materials, such as carbon fibers, carbon nanotubes, carbon microtubes, etc., are recently limited by strict preparation and hard to industrialize. Inspired by the traditional handicraft of candied haw, ZnO/porous carbon micron tubes (ZnO/PCMT), are achieved by conducting a dip-coating and thermal etching process on recycling the abandoned Sycamore microtube. The prepared ZnO/PCMT exhibits higher specific surface area (1076mg) and excellent microwave absorption performance. With a filler loading of only 6.7wt.%, the ZnO/PCMT achieved a great electromagnetic wave absorbing performance. Such excellent ultralight absorption performance can be attributed to their distinct hollow tubular structure of Sycamore based carbon microtube, which can easily construct conductive networks, improving the impedance matching. This work expands a new direction for the development of one-dimensional natural Sycamore microtube as ultra-light and broadband high-performance microwave absorbing materials.
基于碳材料的过度导电性导致阻抗失配,从而阻碍了它们在航空航天和军事领域的电磁吸收应用。而一维碳材料更有利于构建网络,满足阻抗匹配。一维碳材料,如碳纤维、碳纳米管、碳微管等,由于严格的制备条件而受到限制,难以实现工业化。受传统冰糖葫芦工艺的启发,通过对废弃的梧桐微管进行浸涂和热刻蚀处理,制备了 ZnO/多孔碳微管(ZnO/PCMT)。所制备的 ZnO/PCMT 具有更高的比表面积(1076mg)和优异的微波吸收性能。在填充量仅为 6.7wt.%时,ZnO/PCMT 实现了优异的电磁波吸收性能。这种优异的超轻吸收性能可归因于其基于梧桐的碳微管的独特空心管状结构,该结构可轻松构建导电网络,提高阻抗匹配。这项工作为开发超轻和宽带高性能微波吸收材料的一维天然梧桐微管开辟了新的方向。