Single-Step and Room-Temperature Synthesis of Laser-Induced Pt/VC Nanocomposites as Effective Bifunctional Electrocatalysts for Hydrogen Evolution and Oxygen Evolution Reactions.

The development of cost-effective Pt-based electrocatalysts is of great scientific and industrial significance for improving the electrocatalytic activity of hydrogen evolution (HER) and oxygen evolution (OER) reactions for overall water splitting. In this work, unlike traditional furnace pyrolysis, we report the rapid and single-step room-temperature synthesis of Pt/VC nanocomposites with a three-dimensional (3D) network porous structure by laser irradiation technology. The resultant Pt-based composite (Pt/VC-2.84) could be applied to HER under different pH conditions. In particular, the content of Pt in Pt/VC-2.84 is only 2.84 wt %, which is far lower than that in the advanced HER electrocatalyst with the Pt content of 20 wt % (commercial 20 wt % Pt/C). In addition, Pt/VC-2.84 exhibits a boosted higher OER activity and stability than RuO in an alkaline medium. Most importantly, electrocatalytic results reflect that Pt/VC-2.84 reveals superior activity and stability toward overall water splitting.