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铂负载介孔碳球:具有可控结构,催化活性和稳定性增强

Pt incorporated mesoporous carbon spheres: controllable structure with enhanced catalytic activity and stability.

作者信息

Liu Hongyan, Liu Yaling, Da Huimei, Yuan Ruo

机构信息

Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University Chongqing 400715 P. R. China

出版信息

RSC Adv. 2018 Apr 16;8(25):13964-13969. doi: 10.1039/c8ra01453a. eCollection 2018 Apr 11.

Abstract

We report a simple synthesis process to prepare well-dispersed Pt nanoparticles incorporated in mesoporous carbon spheres. By manipulating the relative ratio of Pt precursor and resorcinol-formaldehyde resin (RF), Pt/carbon composites with different morphologies and Pt content were achieved. The as-prepared Pt/C composite materials show higher catalytic activity and reusability for the reduction of 4-nitrophenol (4-NP) than the Pt deposited commercial activated carbon (Pt/AC), which can be ascribed to the high dispersion of Pt nanoparticles in the carbon spheres.

摘要

我们报道了一种简单的合成方法,用于制备负载在介孔碳球中的分散良好的铂纳米颗粒。通过控制铂前驱体与间苯二酚 - 甲醛树脂(RF)的相对比例,制备出了具有不同形态和铂含量的铂/碳复合材料。所制备的铂/碳复合材料对4-硝基苯酚(4-NP)还原反应表现出比负载在商业活性炭上的铂(Pt/AC)更高的催化活性和可重复使用性,这归因于铂纳米颗粒在碳球中的高度分散。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/89fe/9079855/1e6e3318bace/c8ra01453a-f1.jpg

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