• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于蓝紫色无机颜料的Ba(ZnCo)SiO（0≤≤0.50）的合成与表征

Synthesis and characterisation of Ba(Zn Co )SiO (0 ≤ ≤ 0.50) for blue-violet inorganic pigments.

作者信息

Tsukimori Takashi, Shobu Yusuke, Oka Ryohei, Masui Toshiyuki

机构信息

Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University 4-101, Koyama-cho Minami Tottori 680-8552 Japan

出版信息

RSC Adv. 2018 Feb 27;8(16):9017-9022. doi: 10.1039/c8ra00101d. eCollection 2018 Feb 23.

DOI:10.1039/c8ra00101d
PMID:35539865
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9078626/
Abstract

Ba(Zn Co )SiO (0 ≤ ≤ 0.50) solid solutions were synthesized as novel blue-violet inorganic pigments by a conventional solid-state reaction method. The crystal structure, optical properties, and colour of the pigments were characterized. All the pigments were obtained in a single-phase form. The pigments strongly absorbed visible light at wavelengths from 550 to 650 nm, corresponding to the range of green to orange light. This optical absorption was caused by the d-d transition of the tetrahedrally coordinated Co (A(F) → T(P)), which was the origin of the blue-violet colour of the pigments. The most intense colour was obtained for Ba(ZnCo)SiO, where * = +52.2 and * = -65.5 in the CIE (Commission Internationale de l'Éclairage) *** system. These absolute values were significantly larger than those of commercial violet pigments such as Co(PO) (* = +33 and * = -32) and NHMnPO (* = +39 and * = -21). Therefore, the Ba(ZnCo)SiO pigment could be a novel blue-violet inorganic pigment.

摘要

通过传统的固态反应法合成了Ba(Zn1-xCox)SiO4（0 ≤ x ≤ 0.50）固溶体作为新型蓝紫色无机颜料。对颜料的晶体结构、光学性质和颜色进行了表征。所有颜料均以单相形式获得。这些颜料在550至650 nm波长处强烈吸收可见光，对应于绿色到橙色光的范围。这种光吸收是由四面体配位的Co2+的d-d跃迁（A(F) → T(P)）引起的，这是颜料蓝紫色的来源。对于Ba(Zn0.5Co0.5)SiO4获得了最强烈的颜色，在CIE（国际照明委员会）***系统中，x = +52.2且y = -65.5。这些绝对值明显大于商业紫色颜料如Co(PO4)（x = +33且y = -32）和NH4MnPO4（x = +39且y = -21）的绝对值。因此，Ba(Zn0.5Co0.5)SiO4颜料可能是一种新型蓝紫色无机颜料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/033303fe6382/c8ra00101d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/efbf986c27d2/c8ra00101d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/89865290b08d/c8ra00101d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/8ebaf35416ee/c8ra00101d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/e5c18e274db5/c8ra00101d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/84d039f427ba/c8ra00101d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/7405638a55e3/c8ra00101d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/033303fe6382/c8ra00101d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/efbf986c27d2/c8ra00101d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/89865290b08d/c8ra00101d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/8ebaf35416ee/c8ra00101d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/e5c18e274db5/c8ra00101d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/84d039f427ba/c8ra00101d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/7405638a55e3/c8ra00101d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d3/9078626/033303fe6382/c8ra00101d-f7.jpg

相似文献

1
Synthesis and characterisation of Ba(Zn Co )SiO (0 ≤ ≤ 0.50) for blue-violet inorganic pigments.用于蓝紫色无机颜料的Ba(ZnCo)SiO（0≤≤0.50）的合成与表征
RSC Adv. 2018 Feb 27;8(16):9017-9022. doi: 10.1039/c8ra00101d. eCollection 2018 Feb 23.
2
Synthesis and Color Evaluation of Ta-Doped BiO.钽掺杂氧化铋的合成与颜色评价
ACS Omega. 2019 Apr 25;4(4):7581-7585. doi: 10.1021/acsomega.9b00555. eCollection 2019 Apr 30.
3
Novel Orange Color Pigments Based on LaLiMnO.基于 LaLiMnO 的新型橙色颜料。
Molecules. 2021 Oct 15;26(20):6243. doi: 10.3390/molecules26206243.
4
Developing Intense Blue and Magenta Colors in α-LiZnBO : The Role of 3d-Metal Substitution and Coordination.在α-LiZnBO中产生强烈的蓝色和品红色：3d金属取代和配位的作用
Chem Asian J. 2016 Nov 22;11(22):3234-3240. doi: 10.1002/asia.201601124. Epub 2016 Oct 28.
5
Synthesis and Characterization of Ca Eu ZrO as Environmentally Friendly Inorganic Yellow Pigments.Ca Eu ZrO作为环境友好型无机黄色颜料的合成与表征
ACS Omega. 2021 Jan 22;6(4):3411-3417. doi: 10.1021/acsomega.0c05959. eCollection 2021 Feb 2.
6
Cobalt Minimisation in Violet CoPO Pigment.紫色磷酸钴颜料中钴的最小化
Materials (Basel). 2022 Jan 31;15(3):1111. doi: 10.3390/ma15031111.
7
Multifunctional Materials Serving as Efficient Non-Doped Violet-Blue Emitters and Host Materials for Phosphorescence.多功能材料作为高效非掺杂紫蓝光发射体及磷光主体材料
Chemistry. 2021 Jun 21;27(35):9102-9111. doi: 10.1002/chem.202100717. Epub 2021 May 19.
8
Colourfast pigments in silicone hand and maxillofacial prostheses.硅酮手部及颌面修复体中的不褪色颜料。
Prosthet Orthot Int. 2002 Aug;26(2):124-34. doi: 10.1080/03093640208726635.
9
High Near-Infrared Reflective ZnAWO Pigments with Various Hues Facilely Fabricated by Tuning Doped Transition Metal Ions (A = Co, Mn, and Fe).通过调控掺杂过渡金属离子（A = Co、Mn和Fe）轻松制备出具有各种色调的高近红外反射性ZnAWO颜料。
Inorg Chem. 2022 Jan 10;61(1):693-699. doi: 10.1021/acs.inorgchem.1c03448. Epub 2021 Dec 12.
10
Hydrothermal synthesis of dittmarite-group NH(CoMn)PO·HO particles as inorganic violet pigments.水热合成迪特马石族NH(CoMn)PO·HO颗粒作为无机紫色颜料。
RSC Adv. 2024 Jan 8;14(3):1939-1943. doi: 10.1039/d3ra07387d. eCollection 2024 Jan 3.

引用本文的文献

1
Hydrothermal synthesis and characterization of novel yellow pigments based on V doped BiPO with high near-infrared reflectance.基于V掺杂BiPO的具有高近红外反射率的新型黄色颜料的水热合成与表征
RSC Adv. 2018 May 29;8(35):19690-19700. doi: 10.1039/c8ra02406e. eCollection 2018 May 25.

本文引用的文献

1
Mn3+ in trigonal bipyramidal coordination: a new blue chromophore.三角双锥配位中的 Mn3+：一种新的蓝色生色团。
J Am Chem Soc. 2009 Dec 2;131(47):17084-6. doi: 10.1021/ja9080666.
2
Synthesis and spectral characterization of CoxMg1-xAl2O4 as new nano-coloring agent of ceramic pigment.尖晶石型 CoxMg1-xAl2O4 的合成及其光谱特性作为新型陶瓷颜料纳米着色剂。
Spectrochim Acta A Mol Biomol Spectrosc. 2009 Oct 15;74(3):665-72. doi: 10.1016/j.saa.2009.07.024. Epub 2009 Aug 8.