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聚乙烯(PE)、聚苯乙烯(PS)及其双体系对单铝酸锶铕镝基(SrAlO:Eu,Dy)荧光粉表面包覆对该颜料光致发光性能的影响。

The effect of the surface coating of a strontium mono-aluminate europium dysprosium-based (SrAlO:Eu,Dy) phosphor by polyethylene (PE), polystyrene (PS) and their dual system on the photoluminescence properties of the pigment.

作者信息

Tayebi Masumeh, Ostad Movahed Saeed, Ahmadpour Ali

机构信息

Chemical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad Mashhad Iran.

Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad Mashhad Iran

出版信息

RSC Adv. 2019 Nov 27;9(66):38703-38712. doi: 10.1039/c9ra08571h. eCollection 2019 Nov 25.

Abstract

SrAlO:Eu,Dy as a known strontium mono-aluminate europium dysprosium-based phosphor is widely used in paints and coating formulations as a photoluminescence pigment. It has two major drawbacks: improper dispersion in organic-based paints and weak water and moisture resistance. To address the above-mentioned drawbacks, the surface coating of phosphors with polyethylene and polystyrene individually and in combination using a solution technique was performed. The FT-IR spectra showed that the used polymers were coated on the phosphor properly. Also, the EDS spectra showed the presence of elemental carbon for the treated phosphors with different amounts. No regular trend was observed for element ratios when the polyethylene content in the coating layer was reduced from 100 to 0%. Based on the XRD patterns, the crystalline structure of the coated phosphors was not affected by the polymeric coated layer. In the SEM micrographs, the sharp and rough edges of the uncoated phosphor changed to a smooth and soft state for the coated phosphors. The brightness of most of the coated phosphors was independent of time and did not change over a period of 5 minutes after UV irradiation. This property makes the polymeric coated phosphors suitable as photoluminescence pigments in all kinds of paints and coatings.

摘要

作为一种已知的基于单铝酸锶铕镝的磷光体,SrAlO:Eu,Dy作为光致发光颜料广泛应用于涂料和涂层配方中。它有两个主要缺点:在有机基涂料中分散性不佳以及耐水和防潮性较弱。为了解决上述缺点,采用溶液技术分别并用聚乙烯和聚苯乙烯对磷光体进行了表面包覆。傅里叶变换红外光谱表明,所用聚合物已正确包覆在磷光体上。此外,能谱显示不同用量处理后的磷光体中存在元素碳。当涂层中聚乙烯含量从100%降至0%时,元素比例未观察到规律趋势。基于X射线衍射图谱,包覆磷光体的晶体结构不受聚合物包覆层影响。在扫描电子显微镜照片中,未包覆磷光体尖锐粗糙的边缘在包覆磷光体中变为光滑柔软的状态。大多数包覆磷光体的亮度与时间无关,在紫外线照射后5分钟内不变。这一特性使得聚合物包覆磷光体适合作为各类涂料和涂层中的光致发光颜料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8804/9075974/a2f5e6c5c3c5/c9ra08571h-f1.jpg

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