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凹凸棒石/氧化镧纳米复合材料作为钢/钢接触润滑添加剂的摩擦学性能

Tribological properties of attapulgite/LaO nanocomposite as lubricant additive for a steel/steel contact.

作者信息

Nan Feng, Zhou Kaihe, Liu Shuan, Pu Jibin, Fang Yunhui, Ding Wenxuan

机构信息

Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences Ningbo 315201 China

State Grid Zhejiang Electric Power Supply Company Ningbo Power Supply Company Co., Ltd Ningbo 315201 China.

出版信息

RSC Adv. 2018 May 9;8(30):16947-16956. doi: 10.1039/c8ra02835d. eCollection 2018 May 3.

Abstract

Attapulgite is a layered silicate with good friction-reduction and self-repairing properties. In order to further improve its tribological properties, the present work mainly focuses on the preparation of attapulgite/LaO nanocomposite and study on its tribological behaviors. The tribological properties of mineral lubricating oil (150SN) containing attapulgite/LaO nanocomposite were investigated through an Optimal SRV-IV oscillating friction and wear tester. The rubbing surfaces and generated tribofilms were characterized by SEM, EDS, XPS and nanoindentation. Results indicated that the friction-reducing ability and antiwear property of the oil were both remarkably improved by attapulgite/LaO nanocomposite. A tribofilm mainly composed of Fe, FeC, FeO, FeO, FeOOH, SiO, SiO and organic compound was formed on the rubbing surface under the lubrication of oil with attapulgite/LaO nanocomposite. The tribofilm possess excellent self-lubricating ability and mechanical properties, which is responsible for the reduction of friction and wear.

摘要

凹凸棒石是一种具有良好减摩和自修复性能的层状硅酸盐。为了进一步提高其摩擦学性能,本工作主要聚焦于凹凸棒石/LaO纳米复合材料的制备及其摩擦学行为研究。通过Optimal SRV-IV振荡摩擦磨损试验机研究了含有凹凸棒石/LaO纳米复合材料的矿物润滑油(150SN)的摩擦学性能。采用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线光电子能谱仪(XPS)和纳米压痕对摩擦表面和生成的摩擦膜进行了表征。结果表明,凹凸棒石/LaO纳米复合材料显著提高了润滑油的减摩能力和抗磨性能。在含有凹凸棒石/LaO纳米复合材料的润滑油润滑下,摩擦表面形成了主要由Fe、FeC、FeO、FeO、FeOOH、SiO、SiO和有机化合物组成的摩擦膜。该摩擦膜具有优异的自润滑能力和力学性能,这是摩擦磨损降低的原因。

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