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使用路易斯碱尿素和硫脲作为添加剂低温、简单且高效地制备钙钛矿太阳能电池:促进大晶粒生长并提供高达18.8%的功率转换效率。

Low-temperature, simple and efficient preparation of perovskite solar cells using Lewis bases urea and thiourea as additives: stimulating large grain growth and providing a PCE up to 18.8.

作者信息

Hsieh Cheng-Ming, Liao Yung-Sheng, Lin Yan-Ru, Chen Chih-Ping, Tsai Cheng-Min, Wei-Guang Diau Eric, Chuang Shih-Ching

机构信息

Department of Applied Chemistry, National Chiao Tung University Hsinchu Taiwan

Department of Materials Engineering, Ming Chi University of Technology New Taipei City Taiwan

出版信息

RSC Adv. 2018 May 29;8(35):19610-19615. doi: 10.1039/c8ra03175d. eCollection 2018 May 25.

DOI:10.1039/c8ra03175d
PMID:35540970
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9080687/
Abstract

We demonstrated that two Lewis bases - urea and thiourea - acted as efficient additives for CHNH(MA)PbI Cl and MAPbI perovskite solar cells (PSCs) and observed a significant increase in PCE for the MAPbI devices in the presence of 1% urea with a remarkable PCE of 18.8% using an extremely low annealing temperature (85 °C).

摘要

我们证明,两种路易斯碱——尿素和硫脲——可作为CHNH(MA)PbI₃Cl和MAPbI₃钙钛矿太阳能电池(PSC)的有效添加剂,并观察到在1%尿素存在的情况下,MAPbI₃器件的功率转换效率(PCE)显著提高,在极低的退火温度(85°C)下,PCE高达18.8%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/0c46553d418c/c8ra03175d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/3f82bac1e193/c8ra03175d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/234105dd5872/c8ra03175d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/0c46553d418c/c8ra03175d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/3f82bac1e193/c8ra03175d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/234105dd5872/c8ra03175d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d341/9080687/0c46553d418c/c8ra03175d-f3.jpg

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