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利用羧基化碳纳米管掺杂的Nafion基质实现离子聚合物金属复合材料的可调驱动行为。

Tunable actuation behavior of ionic polymer metal composite utilizing carboxylated carbon nanotube-doped Nafion matrix.

作者信息

Ru Jie, Zhu Zicai, Wang Yanjie, Chen Hualing, Li Dichen

机构信息

State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi'an Jiaotong University Xi'an Shaanxi 710049 People's Republic of China

School of Mechanical Engineering, Xi'an Jiaotong University Xi'an Shaanxi 710049 People's Republic of China.

出版信息

RSC Adv. 2018 Jan 15;8(6):3090-3094. doi: 10.1039/c7ra11498b. eCollection 2018 Jan 12.

DOI:10.1039/c7ra11498b
PMID:35541185
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9077514/
Abstract

In this study, we propose to neutralize the relaxation deformation of Nafion-ionic polymer metal composite (IPMC) by slow anode deformation of Flemion-IPMC caused by carboxyl groups (-COOH). Carboxylated carbon nanotubes (CCNT) as -COOH carriers were doped into a Nafion matrix. By adjusting the doping content from 0 wt% to 10 wt%, an IPMC with constant steady-state deformation has been achieved at a critical CCNT content of 2 wt%. Moreover, the increasing rate of the slow anode deformation with the CCNT content is tunable, which is found to be 2.26 mm s %.

摘要

在本研究中,我们提议通过羧基(-COOH)引起的 Flemion 离子聚合物金属复合材料(IPMC)的缓慢阳极变形来抵消 Nafion 离子聚合物金属复合材料(IPMC)的松弛变形。将羧化碳纳米管(CCNT)作为 -COOH 载体掺杂到 Nafion 基体中。通过将掺杂含量从 0 wt% 调整到 10 wt%,在 2 wt% 的临界 CCNT 含量下实现了具有恒定稳态变形的 IPMC。此外,缓慢阳极变形随 CCNT 含量的增加速率是可调的,发现其为 2.26 毫米/秒。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/63d62cdd6e3c/c7ra11498b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/b33a0382fe47/c7ra11498b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/4496dddf2c54/c7ra11498b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/3f06e1ac7b90/c7ra11498b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/7c0d88f0cb7d/c7ra11498b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/63d62cdd6e3c/c7ra11498b-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/b33a0382fe47/c7ra11498b-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/4496dddf2c54/c7ra11498b-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/3f06e1ac7b90/c7ra11498b-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/7c0d88f0cb7d/c7ra11498b-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ca92/9077514/63d62cdd6e3c/c7ra11498b-f5.jpg

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本文引用的文献

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J Mater Chem B. 2013 May 21;1(19):2502-2514. doi: 10.1039/c3tb20243g. Epub 2013 Apr 10.
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Fast electrochemistry of conductive polymer nanotubes: synthesis, mechanism, and application.导电聚合物纳米管的快速电化学:合成、机理与应用。
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用于IPMC致动器的具有增强吸水性和内部通道的磺酸化SiO纳米胶体掺杂全氟磺酸膜。
RSC Adv. 2019 Dec 20;9(72):42450-42458. doi: 10.1039/c9ra07488k. eCollection 2019 Dec 18.
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Rapid preparation of a Nafion/Ag NW composite film and its humidity sensing effect.Nafion/Ag纳米线复合薄膜的快速制备及其湿度传感效应
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Performance Enhancement of Ionic Polymer-Metal Composite Actuators with Polyethylene Oxide.聚环氧乙烷增强离子聚合物-金属复合致动器的性能
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