Zhang Wanrong, Sun Hongguang, Zhu Chao, Wan Kai, Zhang Yu, Fang Zhengping, Ai Zhaoquan
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry of Educational Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University Wuhan Hubei 430062 China
RSC Adv. 2018 Apr 23;8(27):15188-15195. doi: 10.1039/c7ra12875d. eCollection 2018 Apr 18.
In this work, rice straw and soy protein were used to make fiberboard which may replace wood fiberboard. Soy protein isolates (SPI) were modified by epoxidized oleic acid to improve the soy protein adhesive properties such as adhesion strength and water resistance. The effects of NaOH content, the addition of modified-SPI adhesives and fiberboard density on the mechanical and water-resistant properties of the rice straw fiberboards were investigated. FTIR and XRD results of modified SPI indicated the epoxidized oleic acid and soy protein reacted with each other. FTIR and SEM images of rice straw fibers showed that NaOH solution removed the wax layer through chemical etching. The results of investigating mechanical properties and water absorption illustrate that when the soy protein-based adhesives content and density and the hot pressing temperature and pressure of fiberboard are 12%, 0.8 g cm, 140 °C and 6 MPa, respectively, the panels have optimal mechanical and water-resistant performances. Moreover, the panels meet the requirements of chinese medium density fiberboard (MDF) Standard of GB/T 11718-2009. Since biological raw materials are recyclable and biomass, the fiberboard bonded with modified soy protein adhesive has no toxicity and is easily biodegradable. In addition, the rice straw burned to produce haze has been preferably utilized.
在这项工作中,稻草和大豆蛋白被用于制造可替代木质纤维板的纤维板。大豆分离蛋白(SPI)通过环氧化油酸进行改性,以改善大豆蛋白粘合剂的性能,如粘合强度和耐水性。研究了氢氧化钠含量、改性SPI粘合剂的添加量以及纤维板密度对稻草纤维板力学性能和耐水性能的影响。改性SPI的傅里叶变换红外光谱(FTIR)和X射线衍射(XRD)结果表明环氧化油酸与大豆蛋白发生了反应。稻草纤维的FTIR和扫描电子显微镜(SEM)图像显示氢氧化钠溶液通过化学蚀刻去除了蜡层。力学性能和吸水性的研究结果表明,当基于大豆蛋白的粘合剂含量、密度以及纤维板的热压温度和压力分别为12%、0.8 g/cm³、140℃和6 MPa时,板材具有最佳的力学性能和耐水性能。此外,这些板材符合GB/T 11718-2009中国中密度纤维板(MDF)标准的要求。由于生物原料是可回收的生物质,用改性大豆蛋白粘合剂粘合的纤维板无毒且易于生物降解。此外,原本会燃烧产生雾霾的稻草得到了有效利用。