The Suzuki-Miyaura reaction as a tool for modification of phenoxyl-nitroxyl radicals of the 4-imidazole -oxide series.

2-(3,5-Di--butyl-4-hydroxyphenyl)-5-(4-iodophenyl)-4,4-dimethyl-4-imidazole 3-oxide reacts with phenylboronic acid and its substituted derivatives in a cross-coupling reaction of the Suzuki-Miyaura type to form 5-biphenyl derivatives of 4-imidazole--oxide. Interaction of the same compound with B(pin) in the presence of PdCl(PPh) proceeds through the formation of intermediate 1,3,2-dioxoborolane and leads to the product of homocoupling: biphenyl-bis(imidazole). Oxidation of the resultant imidazoles with lead dioxide quantitatively yields stable conjugated phenoxyl-nitroxyl mono- and diradicals, which are of interest as electroactive paramagnetic materials. The crystal structure of the monoradical, 2,6-di--butyl-4-[1-oxido-4-(biphenyl-4-yl)-5,5-dimethyl-1-imidazole-2(5)-ylidene]cyclohex-2,5-dienone, its magnetic susceptibility, EPR spectra of the obtained hybrid radicals in solution, and cyclic voltammetry characteristics of 4-imidazoles were studied.