Yang Haiyan, Jiang Liang, Wang Wei, Luo Zhifang, Li Jing, He Zijuan, Yan Zhiyin, Wang Jiaqiang
National Center for International Research on Photoelectric and Energy Materials, Yunnan Provincial Collaborative Innovation Center of Green Chemistry for Lignite Energy, Yunnan Province Engineering Research Center of Photocatalytic Treatment of Industrial Wastewater, School of Chemical Sciences & Technology, Yunnan University Kunming 650091 China
School of Energy, Yunnan University Kunming 650091 China.
RSC Adv. 2019 Nov 19;9(64):37594-37597. doi: 10.1039/c9ra08339a. eCollection 2019 Nov 13.
Metal-organic framework aerogels (MOAs) embedded with CdS (CdS/MOA(Cr)) synthesized a facile one-pot solvothermal method have a larger surface area than pristine MOA(Cr) and the post-synthesized composite. CdS/MOA(Cr) exhibited 5 times enhancement in the photocatalytic activity than that of pure CdS for Cr(vi) reduction under visible light without adding any sacrificial agent, due to the larger surface area and photosensitazation of MOA(Cr).
通过简便的一锅溶剂热法合成的嵌入硫化镉的金属有机框架气凝胶(CdS/MOA(Cr))比原始的MOA(Cr)和后合成的复合材料具有更大的表面积。由于MOA(Cr)具有更大的表面积和光敏化作用,在不添加任何牺牲剂的情况下,CdS/MOA(Cr)在可见光下对Cr(Ⅵ)还原的光催化活性比纯硫化镉提高了5倍。