Zhao Yuan, Cao Shugang, Li Yong, Zhang Zhenyu, Guo Ping, Yang Hongyun, Zhang Shuwen, Pan Ruikai
State Key Laboratory of Coal Mine Disaster Dynamics and Control, College of Resource & Environmental Science, Chongqing University Chongqing 400030 China
Chongqing Research Institute, China Coal Technology Engineering Group Chongqing 400039 China.
RSC Adv. 2018 Jan 31;8(10):5420-5432. doi: 10.1039/c7ra09346b. eCollection 2018 Jan 29.
Moisture is one of the most important factors that influences coal seepage and coal-bed methane (CBM) extraction. To obtain the water occurrence state and dynamic processes of water change in coal, a series of microscopic observation experiments of Wei Jiagou coal by using field-emission environmental scanning-electron microscopy (ESEM) was conducted under the condition of a fixed point. Afterwards, a mathematical model to explain the influence of water on porosity and permeability was proposed based on the ESEM observations. It was found that there were three main types of water occurrence state: a crescent shape, a full filled shape and an annulus shape, which can provide powerful evidence to explain the influence of water on porosity and starting pressure gradient. As well as this, the box counting reached a minimum at a chamber pressure of 520 Pa and the box counting reduced after water wetting. Based on the mathematical model analysis, the water-occupied area of crescent shapes would reach a peak value with an increase of the contact angle, which has a critical impact on the effective porosity. The influence model that we built matched well with experimental data, which in turn demonstrated the validity of the mathematical model. The prominent combined effect of strain and water saturation appeared on the ridge of the permeability contour, while strains have little influence on permeability at a large initial porosity. Furthermore, a model for contact angle and wetting height was proposed and discussed, and contact angles with different improving fluids were tested. It also can be shown that using better wettability improving-fluid can save the cost of volume and have a good performance on the results of hydraulic technology based on model and experimental tests.
水分是影响煤层渗流和煤层气(CBM)开采的最重要因素之一。为了获取煤中水分的赋存状态及水分变化的动态过程,在定点条件下利用场发射环境扫描电子显微镜(ESEM)对魏家沟煤进行了一系列微观观测实验。之后,基于ESEM观测结果提出了一个解释水分对孔隙度和渗透率影响的数学模型。研究发现,水分赋存状态主要有三种类型:月牙形、全充形和环形,这可为解释水分对孔隙度和启动压力梯度的影响提供有力证据。此外,在腔室压力为520 Pa时盒维数达到最小值,且水润湿后盒维数减小。基于数学模型分析,月牙形的水占据面积会随着接触角的增大而达到峰值,这对有效孔隙度有至关重要的影响。我们建立的影响模型与实验数据匹配良好,这反过来证明了数学模型的有效性。应变和含水饱和度的显著联合效应出现在渗透率等值线的脊线上,而在初始孔隙度较大时应变对渗透率影响较小。此外,还提出并讨论了接触角和润湿高度模型,并测试了不同改善流体的接触角。基于模型和实验测试还可以表明,使用润湿性更好的改善流体可以节省体积成本,并且在水力技术结果方面具有良好性能。