一种具有双重发射以及压致变色和热致变色特性且发射峰随温度大幅红移的柱状层状卤化亚铜基金属有机框架。
A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift.
作者信息
Xin Bingjing, Sang Jianwei, Gao Yi, Li Guanghua, Shi Zhan, Feng Shouhua
机构信息
Jilin Institute of Chemical Technology Jilin 132022 P. R. China.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University Changchun 130012 P. R. China.
出版信息
RSC Adv. 2018 Jan 8;8(4):1973-1978. doi: 10.1039/c7ra11950j. eCollection 2018 Jan 5.
We report a new copper halide-based compound [CuIBrCHN] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at 500 nm and 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound 1 show large red shifts of 120 nm and 72 nm, respectively.
我们报道了一种基于卤化铜的新型化合物[CuIBrCHN]（1），其具有三维双贯穿骨架结构。在290 nm和350 nm激发下，化合物1在500 nm和530 nm处呈现双重发射。随着温度从300 K降至6 K，化合物1的发光性质分别出现了120 nm和72 nm的大幅红移。
Zotero 插件