• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

纳米级氮化钨/氮掺杂碳作为镍铁电池中室温下氢氧复合的高效非贵金属催化剂。

Nanoscale tungsten nitride/nitrogen-doped carbon as an efficient non-noble metal catalyst for hydrogen and oxygen recombination at room temperature in nickel-iron batteries.

作者信息

Huang Lanxiang, Yang Jun, Zhou Wanhai, Liu Kun, Zhu Ding, Chen Yungui

机构信息

College of Materials Science and Engineering, Sichuan University Chengdu 610065 P. R. China

Institute of New Energy and Low-Carbon Technology, Sichuan University Chengdu 610065 P. R. China

出版信息

RSC Adv. 2018 Oct 15;8(62):35343-35347. doi: 10.1039/c8ra06437g.

DOI:10.1039/c8ra06437g
PMID:35547899
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9087214/
Abstract

A nanoscale tungsten nitride/nitrogen-doped carbon (WN/NC) catalyst was synthesized through a facile route, and it exhibited efficient catalytic performance for hydrogen and oxygen recombination at room temperature with an average catalytic velocity of 140 μmol h g and long catalytic life of 954 660 s without decay in the catalytic performance. With the WN/NC catalyst, a nickel-iron battery could be sealed and maintenance-free, and it also exhibited low cost; thus, the nickel-iron battery can be used for large-scale energy storage systems in rural/remote areas.

摘要

通过一种简便的方法合成了一种纳米级氮化钨/氮掺杂碳(WN/NC)催化剂,该催化剂在室温下对氢氧复合表现出高效的催化性能,平均催化速度为140 μmol h g ,催化寿命长达954660秒,催化性能无衰减。使用WN/NC催化剂,镍铁电池可以密封且无需维护,成本也较低;因此,镍铁电池可用于农村/偏远地区的大规模储能系统。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/a4d0cbfefb73/c8ra06437g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/2fbae473a272/c8ra06437g-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/2956d988251b/c8ra06437g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/dd2ab5c237b6/c8ra06437g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/a4d0cbfefb73/c8ra06437g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/2fbae473a272/c8ra06437g-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/2956d988251b/c8ra06437g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/dd2ab5c237b6/c8ra06437g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd1a/9087214/a4d0cbfefb73/c8ra06437g-f3.jpg

相似文献

1
Nanoscale tungsten nitride/nitrogen-doped carbon as an efficient non-noble metal catalyst for hydrogen and oxygen recombination at room temperature in nickel-iron batteries.纳米级氮化钨/氮掺杂碳作为镍铁电池中室温下氢氧复合的高效非贵金属催化剂。
RSC Adv. 2018 Oct 15;8(62):35343-35347. doi: 10.1039/c8ra06437g.
2
Tungsten nitride nanocrystals on nitrogen-doped carbon black as efficient electrocatalysts for oxygen reduction reactions.氮化钨纳米晶体负载于氮掺杂炭黑上作为氧还原反应的高效电催化剂。
Chem Commun (Camb). 2015 Jan 11;51(3):572-5. doi: 10.1039/c4cc07137a.
3
Ultrafine iron-cobalt nanoparticles embedded in nitrogen-doped porous carbon matrix for oxygen reduction reaction and zinc-air batteries.嵌入氮掺杂多孔碳基质中的超细铁钴纳米颗粒用于氧还原反应和锌空气电池。
J Colloid Interface Sci. 2019 Jun 15;546:113-121. doi: 10.1016/j.jcis.2019.03.038. Epub 2019 Mar 18.
4
A hybrid of titanium nitride and nitrogen-doped amorphous carbon supported on SiC as a noble metal-free electrocatalyst for oxygen reduction reaction.一种以碳化硅为载体的氮化钛与氮掺杂非晶碳的混合物,作为用于氧还原反应的无贵金属电催化剂。
Chem Commun (Camb). 2015 Feb 14;51(13):2625-8. doi: 10.1039/c4cc08007f.
5
Rationally Designed Hierarchically Structured Tungsten Nitride and Nitrogen-Rich Graphene-Like Carbon Nanocomposite as Efficient Hydrogen Evolution Electrocatalyst.合理设计的分级结构氮化钨与富氮类石墨烯碳纳米复合材料作为高效析氢电催化剂
Adv Sci (Weinh). 2017 Dec 8;5(2):1700603. doi: 10.1002/advs.201700603. eCollection 2018 Feb.
6
Tungsten Nitride-Cobalt Anchored in N-Doped Ordered Porous Carbon as an Efficient Oxygen Reduction Reaction Electrocatalyst.负载于氮掺杂有序多孔碳中的氮化钨-钴作为一种高效氧还原反应电催化剂
Chem Asian J. 2017 Jan 3;12(1):60-66. doi: 10.1002/asia.201601253. Epub 2016 Nov 30.
7
Cobalt and nitrogen co-doped porous carbon/carbon nanotube hybrids anchored with nickel nanoparticles as high-performance electrocatalysts for oxygen reduction reactions.钴和氮共掺杂的多孔碳/碳纳米管杂化物,锚定镍纳米颗粒作为氧还原反应的高性能电催化剂。
Nanoscale. 2020 Jun 28;12(24):13028-13033. doi: 10.1039/d0nr02773a. Epub 2020 Jun 15.
8
Preparation of NiFe@NC/CC Integrated Electrode and Its Application in Zinc-Air Battery.镍铁@氮掺杂碳/碳布集成电极的制备及其在锌空气电池中的应用。
Front Chem. 2020 Nov 9;8:575288. doi: 10.3389/fchem.2020.575288. eCollection 2020.
9
A high efficiency water hydrogen production method based on CdS/WN composite photocatalytic.一种基于硫化镉/氮化钨复合光催化的高效水制氢方法。
J Colloid Interface Sci. 2022 May;613:652-660. doi: 10.1016/j.jcis.2022.01.014. Epub 2022 Jan 8.
10
Phosphorus-Doped Iron Nitride Nanoparticles Encapsulated by Nitrogen-Doped Carbon Nanosheets on Iron Foam In Situ Derived from Saccharomycetes Cerevisiae for Electrocatalytic Overall Water Splitting.酵母原位衍生的氮掺杂碳纳米片包裹的铁泡沫负载的磷掺杂氮化铁纳米粒子用于电催化全水分解。
Small. 2020 Aug;16(32):e2001980. doi: 10.1002/smll.202001980. Epub 2020 Jul 2.

引用本文的文献

1
The Effect of Annealing Temperatures on Selected Properties of WC/C Coatings, Deposited Using Hexacarbonyl Wolfram in an N-SiH Atmosphere.退火温度对在N-SiH气氛中使用六羰基钨沉积的WC/C涂层选定性能的影响。
Materials (Basel). 2021 Aug 18;14(16):4658. doi: 10.3390/ma14164658.

本文引用的文献

1
Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production.通过在金属有机框架中进行受限渗碳合成的多孔碳化钼纳米八面体用于高效制氢。
Nat Commun. 2015 Mar 11;6:6512. doi: 10.1038/ncomms7512.
2
Tungsten-based catalysts for selective deoxygenation.用于选择性脱氧的钨基催化剂。
Angew Chem Int Ed Engl. 2013 May 3;52(19):5089-92. doi: 10.1002/anie.201209809. Epub 2013 Apr 3.
3
Experimental and theoretical investigation of molybdenum carbide and nitride as catalysts for ammonia decomposition.
碳化钼和氮化钼作为氨分解催化剂的实验和理论研究。
J Am Chem Soc. 2013 Mar 6;135(9):3458-64. doi: 10.1021/ja309734u. Epub 2013 Feb 21.
4
Platinum-like behavior of tungsten carbide in surface catalysis.碳化钨在表面催化中的类铂行为。
Science. 1973 Aug 10;181(4099):547-9. doi: 10.1126/science.181.4099.547.