Tobiasz Piotr, Poterała Marcin, Jaśkowska Eliza, Krawczyk Hanna
Department of Organic Chemistry, Faculty of Chemistry, Warsaw University of Technology Noakowskiego 3 00-664 Warsaw Poland
RSC Adv. 2018 Aug 31;8(54):30678-30682. doi: 10.1039/c8ra04249g. eCollection 2018 Aug 30.
A new approach to the synthesis of asymmetrical cyclic compounds using a stilbene scaffold has been developed. The use of boron trifluoride diethyl etherate as the catalyst, both with and without paraformaldehyde, allows us to obtain new substituted dioxanes, oxanes, cyclic compounds or dimer. The analysis of products was run using experimental and theoretical methods.
已开发出一种使用芪支架合成不对称环状化合物的新方法。使用三氟化硼二乙醚络合物作为催化剂,无论有无多聚甲醛,都能得到新的取代二氧六环、氧杂环烷、环状化合物或二聚体。使用实验和理论方法对产物进行了分析。