Photodeformable Azobenzene-Containing Polyimide with Flexible Linkers and Molecular Alignment.

Azobenzene-containing polyimides (azo-PIs) as photodeformable materials have attracted scientific attention in view of combining photoresponse and high performance (such as excellent mechanical and thermal properties). In the previously reported photodeformation of azo-PIs, polarized blue-green light was utilized to produce concerted motion of azobenzene moieties based on the mechanism of photoinduced reorientation. Herein, we explored a designed azo-PI undergoing photodeformation upon unpolarized light irradiation. The azo-PI film aligned by the hot-stretching process exhibited fast and reversible bending behavior under alternate ultraviolet (UV) and visible (vis) light irradiation, indicating the efficient nano-to-macroscopic propagation of molecular deformation of azobenzene. Besides, the aligned azo-PI film even bent in hot water (80 °C) and hot silicone oil (100 and 120 °C) with UV light irradiation.