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用于通过微波合成的硅嵌入有机发光传感器识别铈（III）和亚硝酸根离子的分子按键控制电路。

Molecular keypad controlled circuit for Ce(iii) and NO ions recognition by μw synthesized silicon-embedded organic luminescent sensor.

作者信息

Kaur Navpreet, Singh Gurjaspreet, Singh Jasbhinder, Singh Akshpreet, Satija Pinky, Kaur Gurpreet, Singh Jandeep

机构信息

Department of Chemistry, Lovely Professional University Phagwara-144411 Punjab India

Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University Chandigarh-160014 India.

出版信息

RSC Adv. 2018 Oct 29;8(64):36445-36452. doi: 10.1039/c8ra07294a. eCollection 2018 Oct 26.

DOI:10.1039/c8ra07294a
PMID:35558915
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9088866/
Abstract

This report demonstrates the mimicking of an electronic circuit diagram towards Ce(iii) ion sensing response supported by molecular keypads. The probe naphthyl based triazole linked silatrane (NTS) was efficiently synthesized using a series of microwave mediated reactions. The luminescent sensor NTS was explored for the ion sensing response towards Ce(iii) ions using DMSO and DMSO : HO 4 : 1 (v/v) as solvent media, respectively. The role of water in Ce(iii) ion sensing was detected as 'turn-off' response that contradicts the 'turn-on' with DMSO. Further, the sensing of NO ions by NTS-Ce(iii) ensemble was associated with blue shift on absorption maxima. These mimicking response studies were sketched as circuit diagrams assisted by molecular keypad behaviour as IMPLICATION output logic gate.

摘要

本报告展示了由分子按键支持的对铈（III）离子传感响应的电子电路图模拟。通过一系列微波介导的反应高效合成了基于萘基三唑连接的硅氮烷（NTS）探针。分别使用二甲基亚砜（DMSO）和DMSO∶水（体积比4∶1）作为溶剂介质，研究了发光传感器NTS对铈（III）离子的离子传感响应。检测到水在铈（III）离子传感中的作用为“关闭”响应，这与DMSO的“开启”响应相反。此外，NTS - 铈（III）组合对硝酸根离子的传感与吸收最大值处的蓝移有关。这些模拟响应研究被绘制成由分子按键行为辅助的电路图，作为蕴含输出逻辑门。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/a52e6a4c0a8f/c8ra07294a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/6a45da160e29/c8ra07294a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/3c787c49b269/c8ra07294a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/1146205f79a2/c8ra07294a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/e3050a590e34/c8ra07294a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/9fce8692732a/c8ra07294a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/5208ee65fa02/c8ra07294a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/29750825228c/c8ra07294a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/1ddcfd267578/c8ra07294a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/12552bfe7496/c8ra07294a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/a52e6a4c0a8f/c8ra07294a-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/6a45da160e29/c8ra07294a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/3c787c49b269/c8ra07294a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/1146205f79a2/c8ra07294a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/e3050a590e34/c8ra07294a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/9fce8692732a/c8ra07294a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/5208ee65fa02/c8ra07294a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/29750825228c/c8ra07294a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/1ddcfd267578/c8ra07294a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/12552bfe7496/c8ra07294a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/694e/9088866/a52e6a4c0a8f/c8ra07294a-f9.jpg

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本文引用的文献

1
Biogenic unmodified gold nanoparticles for selective and quantitative detection of cerium using UV-vis spectroscopy and photon correlation spectroscopy (DLS).使用紫外-可见光谱法和光子相关光谱法（DLS），通过生物合成未经修饰的金纳米粒子对铈进行选择性和定量检测。
Biosens Bioelectron. 2015 Jun 15;68:598-603. doi: 10.1016/j.bios.2015.01.048. Epub 2015 Jan 22.
2
Anion sensing by small molecules and molecular ensembles.小分子和分子聚集体的阴离子传感。
Chem Soc Rev. 2015 Jul 7;44(13):4212-27. doi: 10.1039/c4cs00179f. Epub 2014 Jun 30.
3
Fluoride triggered fluorescence "turn on" sensor for Zn2+ ions based on pentaquinone scaffold that works as a molecular keypad lock.
基于五醌骨架的氟离子触发荧光“开启”传感器用于检测 Zn2+ 离子，该传感器作为分子密码锁工作。
Org Lett. 2012 Jun 1;14(11):2802-5. doi: 10.1021/ol301030z. Epub 2012 May 11.
4
Chemical sensors that incorporate click-derived triazoles.结合点击衍生三唑的化学传感器。
Chem Soc Rev. 2011 May;40(5):2848-66. doi: 10.1039/c0cs00143k. Epub 2011 Mar 4.
5
Luminescent lanthanide complexes as analytical tools in anion sensing, pH indication and protein recognition.作为分析工具的镧系元素配合物的发光特性，用于阴离子感应、pH 指示剂和蛋白质识别。
Analyst. 2011 Feb 7;136(3):431-5. doi: 10.1039/c0an00808g. Epub 2010 Dec 20.
6
One-pot microwave assisted synthesis under green chemistry conditions, antioxidant screening, and cytotoxicity assessments of benzimidazole Schiff bases and pyrimido[1,2-a]benzimidazol-3(4H)-ones.一锅微波辅助法在绿色化学条件下合成、苯并咪唑席夫碱和嘧啶并[1,2-a]苯并咪唑-3(4H)-酮的抗氧化筛选和细胞毒性评估。
Eur J Med Chem. 2011 Jan;46(1):297-306. doi: 10.1016/j.ejmech.2010.11.018. Epub 2010 Nov 19.
7
Library of 1,4-disubstituted 1,2,3-triazole analogs of oxazolidinone RNA-binding agents.恶唑烷酮RNA结合剂的1,4-二取代1,2,3-三唑类似物文库。
J Comb Chem. 2010 Jul 12;12(4):491-6. doi: 10.1021/cc100029y.
8
Phosphorescent chemosensors based on heavy-metal complexes.基于重金属配合物的荧光化学传感器。
Chem Soc Rev. 2010 Aug;39(8):3007-30. doi: 10.1039/b915340c. Epub 2010 May 17.
9
Antioxidant and antiproliferative activities of hydroxyl-substituted Schiff bases.羟基取代席夫碱的抗氧化和抗增殖活性。
Bioorg Med Chem Lett. 2010 Apr 15;20(8):2417-20. doi: 10.1016/j.bmcl.2010.03.039. Epub 2010 Mar 11.
10
Selective manipulation of ICT and PET Processes in styryl-Bodipy derivatives: applications in molecular logic and fluorescence sensing of metal ions.选择性调控苯乙烯基-Bodipy 衍生物中的 ICT 和 PET 过程：在分子逻辑和金属离子荧光传感中的应用。
J Am Chem Soc. 2010 Jun 16;132(23):8029-36. doi: 10.1021/ja1008163.