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一步合成用于光催化产生羟基自由基的双通道途径的高效AgBr-Br-g-CN复合催化剂。

One step synthesis of high-efficiency AgBr-Br-g-CN composite catalysts for photocatalytic HO production two channel pathway.

作者信息

Wang Yunke, Hu Shaozheng, Li Qiang, Gu Guizhou, Zhao Yanfeng, Liang Hongyu, Li Wei

机构信息

College of Chemistry, Chemical Engineering, and Environmental Engineering, Liaoning Shihua University Fushun 113001 China

出版信息

RSC Adv. 2018 Nov 1;8(64):36903-36909. doi: 10.1039/c8ra07749e. eCollection 2018 Oct 26.

Abstract

In this work, a two-component modified AgBr-Br-g-CN composite catalyst with outstanding photocatalytic HO production ability is synthesized. XRD, UV-Vis, N adsorption, TEM, XPS, EPR and PL were used to characterize the obtained catalysts. The as-prepared AgBr-Br-g-CN composite catalyst shows the highest HO equilibrium concentration of 3.9 mmol L, which is 7.8 and 19.5 times higher than that of GCN and AgBr. A "two channel pathway" is proposed for this reaction system which causes the remarkably promoted HO production ability. In addition, compared with another two-component modified catalyst, Ag-AgBr-g-CN, AgBr-Br-g-CN composite catalyst displays the higher photocatalytic HO production ability and stability.

摘要

在本工作中,合成了具有出色光催化产羟基自由基(·OH)能力的双组分改性AgBr-Br-g-CN复合催化剂。采用X射线衍射(XRD)、紫外可见漫反射光谱(UV-Vis)、氮气吸附、透射电子显微镜(TEM)、X射线光电子能谱(XPS)、电子顺磁共振(EPR)和光致发光光谱(PL)对所得催化剂进行表征。所制备的AgBr-Br-g-CN复合催化剂显示出最高的·OH平衡浓度,为3.9 mmol/L,分别是g-CN和AgBr的7.8倍和19.5倍。针对该反应体系提出了“双通道途径”,这导致了显著提高的·OH生成能力。此外,与另一种双组分改性催化剂Ag-AgBr-g-CN相比,AgBr-Br-g-CN复合催化剂表现出更高的光催化产·OH能力和稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fcd/9088936/fdbc8e6e1898/c8ra07749e-f1.jpg

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